从钼酸铵溶液中除去砷的研究-中南大学学报.PDF

42 8 () Vol.42 No.8 2011 8 Journal of Central South University (Science and Technology) Aug. 2011 ( 410083) N235 96.8 g/L8.75 g/L 1.2 297 K30 min 46.7 mg/L0.34% Mg2+0.52 g/L 724 pH 9.2 1 mL/min17 72 mg/L6.58 g/L 2 mol/L HCl 100% TF 803.25 A 1672−7207(2011)08−2193−05 Research on arsenic removal from ammonium molybdate solution YANG Liang, ZHAO Zhong-wei, CHEN Ai-liang, LIU Xu-heng, HUO Guang-sheng (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The coarse ammonium molybdate solution containing Mo 96.8 g/L and As 8.75 g/L was obtained by extracting Mo with N235 from leaching solution of Ni-Mo ore. Arsenic was removed as MgNH4AsO4 after adding magnesium chloride into the solution. The results show that when the dosage of magnesium chloride is 1.2 times of stoichiometric quantity, the reaction temperature is 297 K and the reaction time is 30 min, 99.46% of arsenic is removed, 0.34% Mo is lostand mass concentration of the residual Mg2+ in the solution is 0.52 g/L. Mg2+ is removed from the ammonium molybdate solution with weak acid resin 724. In the solution, the pH value is about 9.2, and mass concentration of Mg2+ is 72 mg/L in the effluent until effluent/resin volume ratio is over 17 at the flow rate 1 mL/min. In addition, the operating exchange capacity of the resin is 6.58 g/L. The loaded resin can be stripped and regenerated with 2 mol/L HCl solution, and the desorption ratio of Mg2+ is almost 100%. Key words: Ni-Mo ore; MgNH AsO ; Mg removal; ion exchange 4 4 Zhao [9] [1−6]