三苯基胺单体合成.pdf

Tetrahedron 66 (2010) 3318–3325 Contents lists available at ScienceDirect Tetrahedron journal homepage: www.el /locate/tet Synthesis of sensitizers containing donor cascade of triarylamine and dimethylarylamine moieties for dye-sensitized solar cells Lu Zhang, Yongkang Liu, Zhongyuan Wang, Mao Liang, Zhe Sun, Song Xue * Department of Applied Chemistry, Tianjin University of Technology, Tianjin 300384, PR China a r t i c l e i n f o a b s t r a c t Article history: Four triarylamine derivatives (XS6–9) containing N,N-dimethylaryl amine units as secondary electron- Received 6 January 2010 donating groups are designed and synthesized. These dyes were applied into nanocrystalline TiO2 Received in revised form 22 February 2010 dye-sensitized solar cells through standard operations. For a typical device the maximal monochromatic Accepted 26 February 2010 incident photon-to-current conversion efficiency (IPCE) can reach 93%, with a short-circuit photocurrent Available online 6 March 2010 2 density (J sc) 10.8 mA cm , an open-circuit photovoltage (Voc) 690 mV, and fill factor (FF) 0.61, which corresponds to an overall conversion efficiency of 4.54%. Keywords: 2010 Elsevier Ltd. All rights reserved. Dye-sensitized solar cell Photovoltaic D