removal of copper ions from acid mine drainage wastewater using ion exchange technique factorial design analysis去除铜离子的酸性矿山废水废水利用离子交换技术的阶乘设计分析.pdf

J. Water Resource and Protection, 2010, 2, 984-989 doi:10.4236/jwarp.2010.211117 Published Online November 2010 (http://www.SciRP.org/journal/jwarp) Removal of Copper Ions from Acid Mine Drainage Wastewater Using Ion Exchange Technique: Factorial Design Analysis 1 2 2 R. W. Gaikwad , R. S. Sapkal , V. S. Sapkal 1 Department. of Chemical Engineering, Pravara Rural Engineering College, Loni, Dist: Ahmednagar (MS), India 2Department of Chemical Technology, Sant Gadgebaba Amravati University, Amravati (MS), India E-mail : rwgaikwad@ Received July 8, 2010; revised July 13, 2010; accepted July 19, 2010 Abstract A factorial experimental design method was used to examine the “Cu2+” removal from acid mine drainage wastewater by ion exchange technique. Ion Exchange technique is preferred because of reduced sludge gen- eration compared to conventional treatment techniques and better decontamination efficiency from highly diluted solutions. Factorial design of experiments is employed to study the effect of four factors pH (3, 5, and 6), flow rate (5, 10, 15 L/hr), resin bed height (20, 40 and 60 cm) and initial concentration of the metal (100, -1 150 and 200 mgl ) at three levels. The efficiency of metal removal was determined after 100 min of treat- ment. Main effects and interaction effects of the four factors were analyzed using statistical techniques. A regression model was recommended and it was found to fit the experimental data very well. The results were analyzed statistically using the Student’s t-test, analysis of variance, F-test and lack of fit to define most im- portant process variables affecting the p