原创力文档the effect of energy levels of the electron acceptor materials on organic photovoltaic cells电子受体材料的能级的影响在有机光伏电池.pdfVIP
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the effect of energy levels of the electron acceptor materials on organic photovoltaic cells电子受体材料的能级的影响在有机光伏电池
Smart Grid and Renewable Energy, 2011, 2, 278-281
doi:10.4236/sgre.2011.23031 Published Online August 2011 (http://www.SciRP.org/journal/sgre)
The Effect of Energy Levels of the Electron
Acceptor Materials on Organic Photovoltaic Cells
Hassen Derouiche*, Sami Saidi, Abdelatif Belhadj Mohamed
Laboratoire de Photovoltaïques, Centre de Recherches et des Technologies de l’Energie, Hammam-Lif, Tunisia.
Email: hderouiche@yahoo.fr, hassenderouiche@isste.rnu.tn
Received March 10, 2011; revised May 21, 2011; accepted May 28, 2011.
ABSTRACT
Organic photovoltaic cells have been fabricated using copper phthalocyanine CuPc as electron donor and C60 or
PCBM as electron acceptor. We have investigated the I-V measurements of two different structures: ITO/PEDOT:
PSS/(CuPc: C60 or CuPc : PCBM)/BCP/Al. We have observed that the substitution of PCBM by C60 scales up the pho-
tocurrent and the efficiency of the devices. As for the open-circuit voltage and the fill factor, we have seen that Voc and
FF depend on the energy difference between the highest occupied molecular orbital (HOMO) of CuPc and the lowest
unoccupied molecular orbital (LUMO) of C60 or PCBM.
Keywords : CuPc, C60, PCBM, Energy Levels, Organic Photovoltaic Cells
1. Introduction The aim of this work is to present the effect of energy
levels of the electron acceptor materials on organic pho-
Organic photovoltaic cells have recently attracted con-
tovoltaic cells and to investigate the implication of the
siderable attention because they are low cost and easy to
electrostatic forces resulting from the energy difference
process [1-
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