涂钽石墨管-石墨炉原子吸收法测定食品中铝含量.PDFVIP

498 2008, Vol. 29, No. 11 食品科学 ※分析检测 1,2 3 2 1 1, 张 岩 ，吕 品 ，李 挥 ，王 多 ，刘敬泽 * (1.河北师范大学生命科学学院，河北 石家庄 050016 ；2.河北省食品安全重点实验室，河北 石家庄 050051 ； 3.河北医科大学基础医学院，河北 石家庄 050017) ：样品经湿法消解后，在基体改进剂作用下，采用涂钽石墨管、塞曼校正石墨炉原子吸收光谱法测定食 品中铝含量。结果表明，铝含量在0 ～50μg/L 范围内呈线性关系，r=0.9996 ，检出限为0.27pg ，加标回收率为 98.6% ～100.5%，相对标准偏差为2.98% 。标准样品测定结果符合要求。该方法快速、灵敏、准确、精密度较 好，适用于食品中铝的测定。 ：涂钽石墨管；石墨炉原子吸收；食品；铝 Determination of Aluminum in Food with Tantalum-coated Graphite Tube-Graphite Furnace Atomic Absorption Spectrometry ： 1,2 3 2 1 1, ZHANG Yan ，LU Pin ，LI Hui ，WANG Duo ，LIU Jing-ze * (1.College of Life Science, Hebei Normal University, Shijiazhuang 050016, China；2.Hebei Key Laboratory of Food Safety, Shijiazhuang 050051, China；3.College of Basic Medical, Hebei Medical University, Shijiazhuang 050017, China) Abstract ：Aluminum in the wet-digested food was determined by tantalum-coated graphite tube-graphite furnace atomic absorption spectrometry with matrix modifier. Results showed that the linear range is between 0 and 50 μg/L with r =0.9996, RSD of 2.98% and recovery rate of 98.6% to 100.5%. The detection limit of the method is 0.27 pg. The sample analysis results measure up. This method is simple, rapid and accurate with satisfactory results. Key words ：tantalum-coated graphite tube ；graphite furnace atomic absorption spectrometry ；food ；aluminum 中图分类号：TS207 文献标识码：A 文章编号：1002-6630(2008)11-0498-03 铝并非人体必需的微量元素。从食品中摄入过量 消解后，用硝酸镁做基体改进剂测定食品中铝，取得