石墨表面金属化对铜基复合材料摩擦学性能的影晌.PDFVIP

第 17 卷第 10 期 中国有色金属学报 2007 年 10 月 Vo l.1 7 No .1 0 The Chinese Journal ofNonferrous Metals Oct. 2007 文章编号 1004-0609(2007) 10-1637-07 石墨表面金属化对铜基复合材料摩擦学性能的影晌 焦明华，尹延国，俞建卫，解挺，杜春宽，刘 媲，吴玉程 (合肥工业大学摩擦学研究所，合肥 230009) 摘 要:利用化学镀技术制备镀铜和镀镰石墨粉，采用粉末冶金复压复烧工艺制备铜基石墨自润滑复合材料，测 试了复合材料的摩擦磨损性能，利用 X 射线衍射、扫描电镜和能谱仪等分析该复合材料的结构、摩擦磨损性能及 机理。结果表明:石墨表面铜、镇镀层改善了石器和铜合金基体界面结合，摩擦过程中所形成的润滑膜与基体粘 附性好，显示出更好的润滑减摩效果，摩擦副摩擦因数由 0.24 降低到 0.20，磨损率降低约 50%; 实验条件下， 6%(质量分数)石墨铜基复合材料经历轻微磨损、中等磨损和严重磨损 3 个磨损过程;而 6%镀铜、镀镰石墨铜基 复合材料只经历轻微磨损和中等磨损两个磨损过程。 关键词:铜:石墨:金属化:复合材料:摩擦学 中图分类号 TH 117.1 文献标识码 A Influence of surface metallization of graphite on tribological properties 。f Cu-matrix/graphite composite materials JIAOMi吨-hua， YIN Yan-guo , YU Jian-wei , XIE Ting, DU Chun-kuan, LIU Kun , WU Yu-cheng (Institute ofTribology, Hefei University cifTechnology, Hefei 230009 , China) Abstract: The graphites coated with copper or nickel were prepared using electroless plating technology. And the Cu-matrixlgraphite composite materials were made by repressing and resintering process of powder meta1 1urgy. The tribologica1 properties of the composites were investigated on a tribometer. The composite structure, wear process and wear mechanism were ana1yzed by XRD , SEM and EDS. The results show that the interfacia1 combination between the graphites and copper-matrix is greatly improved by the graphite particles coated with copper or nickel , resulting in the good adhesion of the lubricating film to matrix. The composites with coated graphite particles exhibit better anti-friction and anti-wear, iιthe coefficient of friction decreases f