污泥活性炭对活性艳红K-2BP染料的吸附特性研究.doc

污泥活性炭对活性艳红K-2BP染料的吸附特性研究 第42卷 Vo1.42 第3期 No.3 山东大学(理学版) JOURNALOFSHDONGUNⅣERS丌Y 2007年3月 Mar.20o7 文章编号:1671—9352(2007}03-0064—07 污泥活性炭对活性艳红K一2BP染料的 吸附特性研究 解建坤,岳钦艳,于慧,岳文文,李仁波,张升晓,王晓娜 (山东大学环境科学与工程学院,山东济南250100) 摘要:以城市污水处理厂脱水污泥作为原料,采用化学活化(ZnC12作为活化剂)制得污泥活性炭,并将其用于吸 附活性艳红K-2BP染料.考察了吸附剂投加量,吸附时间和pH值对吸附效果的影响,并对其吸附动力学和热力学 特性进行了探讨.结果表明,所制得的污泥活性炭的碘吸附值为326mg?g一,产率为51.31%,BET比表面积为 298?g一,具有中孔性和开放的孔结构,浸出液重金属含量不超标;污泥活性炭对活性艳红K-2BP的吸附动力学 符合二阶段吸附速率方程和伪二级动力学方程;此吸附为优惠吸附,Langmuir等温方程比Fleundlich等温方程更适 合于描述此吸附行为;此吸附是一个吸热过程(吸附焓△日gt;0),提高温度有利于吸附的进行,吸附自发进行(吸附 自由能△Glt;0),吸附熵△S总是正值. 关键词:污泥活性炭;活性艳红K-2BP;染料吸附;吸附动力学;吸附热力学 中图分类号:X703文献标识码:A Adsorptivepropertiesofsludgeactivatedcarbonto BrilliantRedK一2BP XIEJian-kun,YUEQin-yan,YUHui,YUEWen.wen, LIRen-bo,ZHANGSheng-xiao,WANGXiao-na (SchoolofEnvironmentalScienceandEngineering,ShandongUniv.,Jinan250100,China) Abstract:SludgeactivatedcarbonWaSpreparedfrommunicipalwastewatertreatmentplantsludgebychemicalactivationwith ZnCl2asanactivationreagent,whichWasusedfortheadsorptionofaye(ReactiveBrilliantRedK-2BP).Theinfluencesofthe adsorbentamount,adsorptiontimeandpHvalueonadsorptioneffectwerestudied.Theadsorptionkinetics,andtheadsorption thermodynamicswerediscussed.Theresuhsindicatethatsludgeactivatedcarbonismesopemusandhasanopenedporousstmc— ture.Theiodineabsorptionvalueofsluageactivatedcarbonis326mgg～,theyieldis51.31%,theBETsurfaceareais 298m2g一,andthecontentofmetalelementsinthelixiviumislowerthanthelimit.TheadsorptionkineticsofReactiveBril. 1iantRedK-2BPthesludgeactivatedcarbonaccordswiththetwo-stepadsorptionkineticsrateequationandpseudo-second-order kineticsequation.ComparedtotheFleundllchisothermequation,theLangmuirisothermequationismoleappropriatetothead— sorpfion.Theadsorptionisanendothemfic(enthalpyAHgt;0)andspontaneous(freeenergyAGlt;0)process,withanincrease inentropy(ASgt;0). Keywords:sludgeactivatedcarbon;ReactiveBrilliantRedK-2BP;dyeadsorption;adsorptionkinetics;adsorptionthermedy— namies 收稿日期:2006-06—27 基金项目:山东省济南市科技发展计划项目(济科合字(20o6)第061073号) 作者简介:解