电解质对镁合金微弧氧化表面膜组织与腐蚀性能的-中国有色金属学报.PDF

第 17 卷第 11 期 中国有色金属学报 2007 年 11 月 Vol.17 No.11 The Chinese Journal of Nonferrous Metals Nov. 2007 文章编号：1004-0609(2007)11-1860-05 电解质对镁合金微弧氧化表面膜组织与腐蚀性能的影响 彭继华，过 萍，李文芳，黄京浩，揭 军 (华南理工大学 机械工程学院，广州 510640) 摘 要：采用SEM、TEM、EDX 、XRD 、AUTOLAB 电化学工作站分析比较两种电解质(硅酸盐体系和有机胺体 系)直流微弧氧化处理AZ91D合金表面涂层的成分、组织结构和涂层的动电位极化曲线。虽然两种电解质体系涂 层元素成分和组成相相同，均为金属相、MgO相和Mg SiO 相，但有机胺电解质体系的涂层中非金属相(MgO 、 2 3 Mg SiO )相对含量高于硅酸盐处理体系，有机胺体系获得的涂层表面均匀致密性也优于硅酸盐体系。有机胺体系 2 4 获得的涂层在3.5% NaCl 中性介质中的腐蚀电流密度、腐蚀电压分别为0.29 μA/cm2 和522 mV，与硅酸盐体系处理 涂层相比，前者的抗腐蚀能力有很大幅度的提高。 关键词：镁合金；微弧氧化；电解质；有机胺；腐蚀 中图分类号：TG 174.451 文献标识码：A Effect of electrolyte on microstructure and corrosion resistance of micro-arc coatings of AZ91D magnesium alloy PENG Ji-hua, GUO Ping, LI Wen-fang, HUANG Jing-hao, JIE Jun (College of Mechanical Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: By means of SEM, TEM, EDX, XRD and AUTOLAB, the composition, constituent phase, microstructure and corrosion resistance of two micro-arc coatings were investigated, which were treated in two electrolytes: organic amine system and silicate solution. The results show that the constituent phases in coatings from two electrolyte are the same, i.e., α/β-Mg, MgO and Mg SiO ; the relative fraction of ceramic phases in the coating from organic amine is higher, and 2 4 the coating surface morphology looks finer and denser than those from silicate solution. According to the potential-dynamic polarization curves in 3.5% NaCl solution, the corrosio