NiAl共晶合金的高温氧化行为的研究+文献综述.docVIP

NiAl共晶合金的高温氧化行为的研究+文献综述 摘要：长程有序金属间化合物NiAl具有熔点高、密度低、抗氧化性好、导热率高、杨氏模量高等一系列特点，但其室温塑性差和高温强度低等缺点，限制了它的应用。因此，人们就通过定向凝固方法制备NiAl -Cr(Mo)合金，并在NiAl-Cr(Mo)基体中加入适量的Hf元素，形成Heusler相进行沉淀强化，得到一种新型的NiAl基共晶合金，本论文采用静态增重法研究NiAl-Cr(Mo) -Hf-Ho合金在900℃的恒温氧化行为，测定其氧化动力学曲线，其氧化动力学曲线近似符合抛物线规律。借助于X-射线衍射仪、扫描电镜和能谱分析表明，该合金表面形成了Cr2O3、A12O3、HfO2复合氧化膜，加入微量的活性元素Hf、Ho有利于改善表面氧化膜的黏附性和抗剥落能力，使该合金具有良好的抗氧化性能。5114 关键词：NiAl共晶合金；高温氧化；氧化动力学; High Temperature Oxidation Behavior of a NiAl Eutectic Alloy Abstract：Long-range ordered intermetallic compound NiAl has a high melting point，low density，good oxidation resistance，high thermal conductivity，high Young #39;s modulus range of characteristics．But its application is limited because of its poor ductility at room temperature and low high temperature strength at high temperature．Therefore，NiAl-Cr (Mo) alloys have been prepared by directionally solidified method．A new type of NiAl -based eutectic alloy is obtained through an appropriate amount of Hf，Ho element has been added to NiAl-Cr (Mo) substrate，forming Heusler phase precipitation strengthening．NiAl-Cr (Mo)-Hf-Ho alloy at 900℃ for the isothermal oxidation behavior was studied by using a static weight increase，the oxidation kinetics were measured．The results indicate that oxidation kinetics approximately obey the parabolic law．The oxidation scales on the surface were determined by means of XRD，SEM and EDS．The results show that oxidation scale was consisted of Cr2O3，A12O3，HfO2 on the surface of the alloy．Surface oxidation scale adhesion and anti-stripping capability is improved by the addition of small amounts of active elements Hf，Ho．So that the alloy has good oxidation resistance． 长程有序金属间化合物NiAl具有熔点高（1638℃约比镍基高温合金高300℃）、密度低（约为镍基高温合金的三分之二）、抗氧化性好、导热率高（约为镍基高温合金的4-8倍）、杨氏模量高等一系列特点，作为高温合金材料具有很强的竞争力，有着广泛的应用前景，但室温脆性限制了其应用[2]。为此，人们采用微合金化、宏合金化和改进工艺等方法来改进NiAl的综合性能，并取得了一定的成效，其中通过复相化改善NiAl的室温断裂韧性的方法受到了广泛的重视。 NiAl合金的结构特点使得它在原子能工业，催化工业以及电子工业领域有着潜在的应用前景。为此，全世界各国材料科学工作者30多年来对NiAl及其合金开展了广泛的研究和应用研究。 1.2 NiAl的物理性质 NiAl是Hume-