壁纸涂层水性树脂的研制+文献综述.docVIP

壁纸涂层水性树脂的研制+文献综述 摘要本论文通过对水性酮肼交联丙烯酸酯树脂、叔碳丙烯酸酯树脂、N-羟甲基丙烯酰胺交联丙烯酸酯水性树脂的制备，研制了用于各类壁纸涂层用的水性树脂，包括水性发泡树脂体系和紫外固化树脂体系。测定了各类水性树脂体系的固含量、粘度、耐水性、耐酸性、耐碱性、耐醇性、耐摩擦性能，并进行了红外表征。研究表明，N-羟甲基丙烯酰胺交联树脂具有较强的耐水性、耐酸性、耐碱性、耐醇性；水性酮肼交联树脂涂层具有高光泽度；紫外固化交联树脂具有较强的硬度；分别适用于不同要求的壁纸涂层。8765 关键词：水性酮肼交联丙烯酸酯树脂；水性叔丙树脂；水性N-羟甲基丙烯酰胺交联丙烯酸酯树脂；紫外固化；光泽度；发泡 The study on the Waterborne resins used on wallpaper Abstract In this paper,by preparing an aqueous hydrazine one crosslinked acrylic resin，Tert-ethylene carbonate acrylate resin，N-methylol acrylamide crosslinked acrylate，Wallpaper was developed for the various types of water-based resin coating.Including water-foamed resin systems and UV-curable resin systems,completing the determination of various water-based resin solid content,viscosity,water resistance, acid resistance, alkali resistance, alcohol resistance, abrasion performance and other properties as well as on all kinds of resins for infrared characterization of lipid membranes.Research shows that N-methylol acrylamide crosslinked resin has a strong water resistance, acid resistance, alkali resistance, alcohol resistance.One hydrazine aqueous crosslinked resin coating has a high gloss. UV curing crosslinked resin having strong hardness. They are suitable for different requirements of wallpaper coatings. Keywords: waterborne ketone hydrazine crosslinking acrylic resin;Versatate acrylic resin;N-methylol acrylamide cross-linked acrylic ester resin;UV curing;Gloss;Foam 目录 1 绪论1 2.5.3水性树脂DMA测定15 2.5.4水性树脂红外测试16 2.5.5水性树脂耐水性测试16 2.5.6水性树脂光泽度的测定16 2.5.7水性树脂耐醇性测试16 2.5.8水性树脂耐酸性测试16 2.5.9水性树脂耐碱性测试17 2.5.10水性树脂耐摩擦性测试17 2.5.11水性树脂铅笔硬度测试17 3结果与讨论18 3.1高性能壁纸涂层水性树脂体系的选择18 3.2 水性叔丙体系树脂的性能研究19 3.2.1水性叔丙体系的红外表征19 3.2.2不同水性叔丙树脂的Tg19 3.2.3水性叔丙树脂单体对性质的影响20 3.2.4不同水性的叔丙树脂的基本性能20 3.2.5 不同水性叔丙树脂的耐介质性能21 3.2.6 不同水性叔丙树脂的光泽度和耐磨差性21 3.3 水性酮肼交联树脂的性能表征22 3.3.1水性酮肼交联树脂的红外表征22 3.3.2水性酮肼交联树脂的DMA表征23 3.3.3水性酮肼交联树脂核壳的玻璃化温度23 3.3.4 水性酮肼交联树脂的基本性能23 3.3.5 水性酮肼交联树脂的耐介质性能24 3.4 水性N-羟甲基丙烯酰胺交联树脂24 3.4.1 水性N-羟甲基丙烯酰胺交联树脂结构的红外表征：24 3.4.2 水性N-