涡阳花沟西10号煤中微量元素的有机亲和性-煤田地质与勘探.PDF

第38 卷 第4 期 煤田地质与勘探 Vol. 38 No.4 2010 年8 月 COAL GEOLOGY EXPLORATION Aug. 2010 文章编号: 1001-1986(2010)04-0016-05 涡阳花沟西 10 号煤中微量元素的有机亲和性 陈 健，刘文中，陈 萍 (安徽理工大学地球与环境学院, 安徽 淮南 232001) : 为研究淮北矿区涡阳花沟西勘查区 10 号煤中微量元素的有机亲和性，共采集 10 个勘探钻 孔煤样品，采用电感耦合等离子质谱仪ICP-MS 分析了 12 种微量元素的含量；应用LECO 碳硫分 析仪测定了煤的总有机碳 TOC ，并通过两者的相关关系分析了元素的有机亲和性，结合元素的地 球化学特征和煤样XRD 物相鉴定结果，通过聚类分析进一步推断元素的赋存状态。结果表明：V 、 Cr 、Co 、Ni 、Mo 、Cd 、Sb、Pb 和Zn 元素含量低于全国均值，没有异常富集，Be 、Cu 和Tl 略高 于全国均值；Cd 具有较强的有机亲和性，Co 、Zn 、Be 和 Cr 的有机亲和性较弱，V 、Ni 、Cu 、 Mo 、Sb、Pb 和Tl 不具有机亲和性；V 、Sb、Cu 、Cr 、Pb 、Co 和Ni 主要以铝硅酸盐吸附态赋存， Cd 主要以有机结合态赋存。 ：微量元素；总有机碳；有机亲和性；赋存状态；煤 ：X141 ：A DOI: 10.3969/j.issn.1001-1986.2010.04.004 Organic affinity of trace elements in coal from No.10 coal-bed at western Huagou, Guoyang CHEN Jian, LIU Wenzhong, CHEN Ping (School of Earth and Environment, Anhui University of Science and Technology , Huainan 232001, China) Abstract: In order to study the organic affinity of trace elements in coal from No.10 coal-bed at western Huagou, Guoyang, 10 borehole samples were collected at exploration area of Huaibei mining area. The contents of 12 kinds of trace elements were determined by the inductively coupled plasma mass spectrometry (ICP-MS), the total or- ganic carbon (TOC) of coal was determined by LECO carbon and sulfur analyzer, and the organic affinity of trace elements were deduced from the correlations between contents and TOCs. Then combined with the geochemical characteristics of trace elements and results of X-ray diffraction, the occurrences of trace elements were further re- searched by cluster analy