台大公共卫生学院-职业医学与工业卫生研究所.pdf

臺大公共衛生學院 職業醫學與工業衛生研究所 103學年度下學期 海報論文研討會論文集 博 士 班 姓名中( /英) 何紀璋/Chi-Chang Ho 學號 碩博班 /年級 博六 (如碩二) 論文題目 大氣戴奧辛之時空間變異及成因分析-化學質量平衡 （中文） 模式之應用 論文題目 Spatial-temporal variation and source apportionment of （英文） long-term ambient PCDD/Fs measurements using chemical mass balance model 摘要 Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) have been monitored in the flue gas from solid waste incinerators, Crematories, iron and steel factories, and the emissions from traffic vehicles and rice straw burning. However, few studies have been estimated the effect of various types of sources to ambient PCDD/F concentration, including local specific sources and line sources. Total of 334 samples were collected from previous investigations conducted from 2003 to 2009. Each sample 3 was continuously collected in three days with 0.225 m /min of sampling flow rate by PS- 1 samplers and analyzed by a high-resolution gas chromatographs/high-resolution mass spectrometers (HRGC/HRMS). Chemical mass balance model was utilized to identify and quantify possible major sources and its source contributions. The preliminary results 3 3 showed that total PCDD/Fs concentration was 0.611 pg/m (0.036 I-TEQ pg/Nm ), and 3 OCDD was the dominant species with the highest average of 0.188 pg/