利用油页岩渣制备微晶玻璃-JournalofNortheasternUniversity.PDF

第29 卷第10期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol29, No. 10 2 00 8 年 10 月 Journal of Northeastern U niversit ( Natural Science) Oct. 2 0 0 8 李 勇, 冯宗玉, 杨 合, 薛向欣 ( , 110004) : , DTA, XRD SEM , : ( T iO + P O ) ; : 850 100 min, 980 80 min 2 2 5 , ; ; : ; ; ; ; : T Q 17 1 : A : 1005-3026( 2008) 10- 1450-05 Preparation of Glass- Ceramics from Oil Shale Residue L I Yong , FEN G Zong-yu , YA N G H e, X UE X iang-x in ( School of Materials and Metallurg , Northeastern Universit , Shen ang 110004, China. Correspondent: XUE X iang-x in, E-mail: xuexx @ mail. neu. edu. cn) Abstract: A glass-ceramics w as prepared w ith oil shale residue as primar material. The compositions of glass-ceramics and selection of both main cr stallization and nucleating agents w ere discussed. T he effects of nucleating agents and heat treatment procedure on glass-ceramics w ere anal zed b means of DTA, XRD and SEM. The results showed that the composite nucleating agent TiO + P O can efficientl step up the cr stallization of such a glass-ceramics. 2 2 5 T he optimal heat treatment procedure w as found as nucleating at 850 for 100 min and the cr stallizing at 980 for 80 min. T he major and minor cr stallization phases of the glass-ceramics is hedenbergite and anorthite, respectivel . T here are several peaks found in the infrared absorption band, and the cr stals present fibrous structures in staggered distribution. The service performance of the glass-ceramics thus prepared is evidentl better than that of other building and decorative materials, such as ceramic tile, marble and granite. Key words: