影响玻璃化学钢化盐浴活性因素研究.pdfVIP

第32 卷第1 期 玻璃与搪瓷 V ol. 32 No. 1 2004 年2 月 GLA SS ENA MEL Feb. 2004 12 1 1 王海风 , 韩文爵 , 王依民 ( 1. , 20005 1; 2 . , 0 30024) : 研究了盐浴的失活与复活分别选择不锈钢银铝和铜作为 应容器的材料, 发现不锈钢 和铜质容器容易受到硝酸钾和亚硝酸钾熔液的腐蚀, 而银和铝则相对稳定经过硝酸钾和亚硝 酸钾钢化处理后的玻璃表面应力层厚度有很大差别硝酸钾熔液在使用初期会暂时失去活性, 失活的熔液在经过时效处理后能够复活; 而使用亚硝酸钾的过程中却没有发现失去活性的现象 分析了失活机理并根据这一机理选择了活化剂 : 化学钢化; 离子交换; 活性; 老化处理; 表面应力层 : T Q171. 6+ 82 : A : 1000- 287 1( 2004) 0 1- 0019- 04 Study on the Activity of Molten Salts Baths for Ion Exchange Strengthening Glass WA N G H ai f eng , H A N Wen j ue, WA N G Yi m in ( 1. College of M ater al Sc ence and Eng neer ng, Dong hua U n vers t y, Shangha 200051, Ch na; 2 . College o f M ater al Sc ence and Eng neer ng, Shanx U n v ers ty of T echnology, T a yan 030024, Ch na) Abstract:Deact vat on and react vat on of salt bat hs are st ud ed. Sta nless steel, s lver, alum num and copper are chosen as react on cont a ner m at er als. It w as f ound t hat st a nless st eel and copper are eas ly eroded by molten pot ass um n t rate and potass um n tr t e, w h le s lver and alum num cont a ners are much more st able. T he th ckness of surface stress layer s very d fferent bet ween t he glasses strengt hened by pot ass um n t rate and pot ass um n t r te. T he molten pot ass um n t rat e loses ts act vat on at t he beg nn ng of on exchange process, w hereas t he deact vated baths can be react vat ed by ag ng treat ment. Deact vat on s not found dur ng t he on ex chang e by us ng molten potass um n t r t e. T he mechan sm of dea