多孔玻璃粉在蒸汽相中自转晶合成含硼CF22沸石-上海有机化学研究所.PDF

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 7 期 , 1346～1349 ACTA CHIMICA SINICA No. 7 , 1346 ～1349 ·研究简报· 多孔玻璃粉在蒸汽相中自转晶合成含硼 CF2 沸石 a a b a , a 董维阳 　　任　瑜 　　邱锡鹏 　　周伟正 　　龙英才 ( a 复旦大学 　化学系分子催化与创新材料实验室 　上海 200433) ( b 复旦大学 　计算机科学与工程系 　上海 200433) 摘要 　在甲胺和水的蒸汽相中 ,多孔玻璃粉自转晶为高结晶度纯相含硼 TON 类型的 CF2 沸石. 11B MAS NMR 证明 硼原子基本上进入了沸石骨架. 扫描电镜照片显示 ,合成的 CF2 沸石中既有单个晶体 ,也有由许多单个晶体构成的 扇形聚集体. 单个晶体呈长条形. 关键词 　含硼 CF2 ,沸石 , 自转晶合成,多孔玻璃粉 ,蒸汽相 ,XRD , 11B MAS NMR , SEM Synthesis of Boroncontaining CF2 Zeolite by Selftransformation of Porous Glass Granules in a Vapor Phase DONG, WeiYang a 　　REN , Yu a 　　QIU , XiPengb 　　ZHOU , WeiZheng a 　　LONG, YingCai , a ( a Laboratory of Molecular Catalysis and Innovative Materials , Department of Chemistry , Fudan University , Shanghai 200433) ( b Department of Computer Science and Engineering , Fudan University , Shanghai 200433) Abstract 　Boroncontaining CF2 zeolite with high crystallinity and purity , which is first reported , was 11 synthesized by selftransformation of porous glass granules in the vapor phase of methylamine and water. B MAS NMR spectra prove that the atoms of B in the raw glass have been essentially completely incorporated into the zeolite framework. The assynthesized crystals of CF2 zeolite are rectangular rodshaped. Some of the crystals are individuals and th