北京典型溶剂使用企业VOCs排放成分特征.PDF

中国环境科学 2015,35(2) ：374~380 China Environmental Science 北京市典型溶剂使用企业 VOCs 排放成分特征 * 莫梓伟,陆思华 ,李 悦,邵 敏,屈 航 (北京大学环境科学与工程学院,环境模拟与污染控制国家重点联合 实验室,北京 100871) 摘要：通过罐采样-GC-MS/FID 采集及分析系统,测定了北京市工业区内典型溶剂使用企业挥发性有机物(VOCs)的排放成分.结果表明:在 汽车喷涂企业中,芳香烃(22%~55%)和烷烃(13%~44%)是重要的 VOCs 排放组分, 印刷企业排放的主要组分为烷烃(43%~71%)和含氧 VOCs(17%~19%), 电子光刻企业排放的特征组分是丙酮(10%~18%),但不同电子光刻企业 VOCs 其它组分比例相差较大;企业中采用的 VOCs 处理装置对 VOCs 排放组成有重要影响;与已有研究的源谱比较,印刷行业源谱较相似,主要以烷烃为主,也有部分芳香烃.汽车喷涂行 业的源谱有很大变化,可能是由于汽车涂料成分改变而造成. 关键词：溶剂使用；VOCs ；源成分谱；处理设施 中图分类号： 文献标识码：A 文章编号：1000-6923(2015)02-0374-07 Emission characteristics of volatile organic compounds (VOCs) from typical solvent use factories in Beijing. MO * Zi-wei, LU Si-hua , LI Yue, SHAO Min, QU Hang (State Joint Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871). China Environmental Science, 2015,35(2)：374~380 Abstract ：VOC emission compositions from solvent use factories in Beijing were measured using canister-GC-MS/FID analysis system. Aromatics (22%~55%) and alkanes (13%~44%) were major species in auto-painting factories while alkanes (43%~71%) and oxygenated VOCs (17%~19%) were dominant in printing factories. VOC species emitted from electronic lithography industries were characterized as high content of acetone (10%~18%), while the proportion of other VOC components were quite discrepancy as to different manufacturers. VOCs treatment facilities, such as the catalytic combustion system, could re-shape the VOC profiles from the factories. Comparing with previous studies, our results showed that the printing profiles were similar, in which alkanes and aromatics we