Chart two-1(逐步聚合).ppt

Melt polycondensation Solution polycondensation Interfacial polycondensation Monomer, catalyst and molecular weight regulator调节剂 Being carried out above the melt point of monomer and polymer Characteristics Simple crafts工艺, intermittent间歇的 or continuous High Temperature, 200℃～300℃ 3. Long reaction time An inert gas is usually necessary for reducing the byproducts The last stage of reaction should be carried out at high vacuum Industrially Covering all the polymers whose melt points are less than 300 oC It does not work well for the high melt point polymer and the high temperature decomposable polymer The bulk polycondensation products can be processed directly Example: Terylene 涤纶, Polycarbonate In solvent Low temperature and mild condition Good heat transmission传热 High vacuum is not necessary Shortcomings: high cost, low efficiency of equipments, de-solvent crafts The reactions are conducted at interface between two immiscible不能混合的 liquids. Irreversible multi-phase polymerization High active monomer and high reaction rate The moderate适度的 mixing is necessary Characteristics Low temperature, high reaction rate, high molecular weight products Simple equipment Convenient方便的 operation Purity and feed ratio of monomers need not strictly controlled. Shortcomings: high cost for the monomer and solvent recycling Example: polycarbonate Fig. 2-2 Polyesterification of adipic acid with diethylene glycol at 109C catalyzed by 0.4 mol% p-toluenesulfonic acid. Discussion 1. data processing： Drawing a plot of versus t，the plot should be linear. The value of k2 can be obtained by the rake ratio. 2. The general linearity of the plot as P≥0.8 confirms that the second reaction order and the concept of indepence of the functional group reactivity on the molecular size. The nonlinearity in the initial region of External-Catalyzed system catalysis reaction is, like that in Self-Catalyzed system, the characteristics of esterifications rather than polyesterifications.