光-Fento剂降解模拟电镀废水中有机物的研究.PDFVIP

安徽农业大学学报, 2011, 38(2): 305-308 Journal of Anhui Agricultural University [DOI]CNKI: 34－1162/S0941.008 光-Fenton 试剂降解模拟电镀废水中有机物的研究 张 卿，吕文英，刘国光，黄春桃 (广东工业大学环境科学与工程学院，广州 510006) 摘 要：采用光-Fenton 高级氧化技术对模拟电镀有机物废水进行氧化处理。通过试验比较单独UV 、单独Fenton 试剂与光-Fenton 体系对废水处理的影响及动力学研究，并对光-Fenton 反应的最佳条件进行了探索。结果表明，紫 外光与Fenton 试剂存在协同效应，紫外光的引入能提高Fenton 试剂处理有机物的效率；随着反应时间的延长，废 水COD 去除率增大，在反应时间为6 min, H O 加入量为理论投加量Q ，Fe2+与H O 摩尔配比为 1:10 时，COD 去 2 2 2 2 除率达到94%以上，且反应在pH 在2~7 之间具有较宽的应用范围。 关键词：紫外光；Fenton 试剂；电镀废水 中图分类号：X781.1 文献标识码：A 文章编号：1672−352X (2011)02−0305−04 Removal of electroplating organic pollutants by UV-Fenton reagent ZHANG Qing, LV Wen-ying, LIU Guo-guang, HUANG Chun-tao (Faculty of Environmental Science and Engineering, Guangdong University of Technology, Guang zhou 510006) Abstract: UV-Fenton reagent was used to treat the organic pollutants in electroplating waste water. The UV process, Fenton process and UV-Fenton process were compared, and the effect of operating parameters of UV-Fenton reaction, such as pH, amount of Fenton’s reagent (H O and FeSO ), and reaction time were deter- 2 2 4 mined. The best operating conditions were determined as that the amount of H 0 at the equivalent of COD, the 2 2 2+ Fenton reagents proportion(Fe : H 0 )about 1/10(molecule ratio), and 6 min for reaction time. The COD removal 2 2 rate was as high as 94.6 ％, and the pH of waste water was between 2－7 under this condition. The results indicate that the treatment of electroplating organic pollutants by UV-Fenton reagen