氮在fe-cr-mn合金体系中的溶解度计算模型-journalof.pdf

第29 卷第4期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol29, No. 4 2 00 8 年 4 月 Journal of Northeastern U ni ersity( Natural Science) Apr. 2 0 0 8 Fe-C-r Mn 李花兵, 姜周华, 张祖瑞, 许宝玉 ( , 110004) : , Fe-Cr-Mn 18Cr- 18Mn , , , , , , : ; Fe-Cr-Mn; ; : T F 02 : A : 1005-3026( 2008) 04-0549-04 Thermodynamic Model to Calculate Nitrogen Solubility in Fe- Cr-Mn Alloys L I H ua-bing , JIA N G Zhou-h ua, ZH A N G Z u-r ui, X U B ao-y u ( School of Materials Metallurgy, Northeastern Uni ersity, Sheny ang 110004, China. Correspondent: LI Hua- bing, E-mail: huabing li @ 163. com) - Abstract : A thermodynamic model to calculate nitrogen solubility in different phases of Fe-Cr-Mn alloy system w as de eloped on the basis of earlier w orks and regular melt model. T he calculation results of 18Cr- 18Mn alloy show ed that the nitrogen solubility in different phases increases w ith increasing nitrogen partial pressure, and the ferrite zone becomes smaller e en disappears. So increasing nitrogen partial pressure can pre ent the porosity forming during solidification. Increasing properly the contents of component elements of austenite in the melts, the ferrite zone where the nitrogen solubility is low becomes smaller e en disappears during the solidification of the melt, thus decreasing the potential nitrogen precipitates during solidification. The calculation results are in good agreement w ith w hat w ere done in earlier w orks. Key words: nitrogen solubility; Fe-Cr-Mn; high nitrogen stainless steel; thermodynamic calculation model