热处理盐浴有害固体废物无害化处理方法（Harmless treatment method of heat treatment salt bath harmful solid waste）.docVIP

热处理盐浴有害固体废物无害化处理方法（Harmless treatment method of heat treatment salt bath harmful solid waste） Harmless treatment method of heat treatment salt bath harmful solid waste JB / T 6047 - 92 Peoples Republic of China machinery and electronics industry 1992 - 05 - 05 approved the implementation of 1993 - 07 - 01 1, the subject content and scope of application This standard specifies the chemical treatment process and safety technical requirements of heat treatment salt bath harmful solid waste. This standard applies to the heat treatment of salt bath harmless treatment of hazardous solid waste, barium salt slag, slag and slag cyanide salt nitrate. 2 citation criteria GB 7487 ISO nicotinic acid - pyrazole colorimetric method ZB Z71 001 general provisions for the management of hazardous solid waste pollution in heat treatment bath salts 3 basic methods Chemical precipitation method and oxidation method were adopted to treat three kinds of waste residue of heat treatment and salt bath. 3.1 types and sources of salt bath waste The types and sources of salt bath waste are shown in table 1. Table 1 Species origin Barium salt residue Nitrate residue High and medium temperature salt bath of cyanogen salt residue Isothermal, graded quenching and tempering bath salt Carbonitriding, liquid carburizing, nitrocarburizing, sulfur and nitrogen nitrocarburizing, carbonitriding, carbonitriding, and other salt bath 3.2 barium salt residue treatment Using precipitation Ba2+ method and adding precipitant Na2SO4 or Na2CO3+H2SO4, the soluble poisonous barium salt is converted into nontoxic barium sulfate precipitate which is insoluble in water. The chemical reaction is as follows: (1) or (2) 3.3 nitrate residue treatment Using oxidation method and adding oxidant NaClO, the toxic nitrite dissolved in water can be oxidized to non-toxic nitrate solution. The chemical reaction is as follows: (3) 3.4 cyanide salt residue treatment The Fe2+ complex and Fe3+ direct reaction method were added into the