钴_镍萃取分离原理与方法_肖超（_ cobalt nickel extraction separation principle and method of _ Xiao Chao）.docVIP

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钴_镍萃取分离原理与方法_肖超（_ cobalt nickel extraction separation principle and method of _ Xiao Chao）.doc

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钴_镍萃取分离原理与方法_肖超（_ cobalt nickel extraction separation principle and method of _ Xiao Chao）

钴_镍萃取分离原理与方法_肖超（_ cobalt nickel extraction separation principle and method of _ Xiao Chao） Twenty-ninth volume fourth issue (total 116th issues) December 2010 Hydrometallurgy Hydrometallurgy of China Vol.29 No.4 (Sum.116) Dec.2010 Principle and method of extraction separation of cobalt and nickel Xiao Chao, Xiao Lian (School of Metallurgical Science and engineering, Central South University, Hunan, Changsha 410083, China) Abstract: cobalt and nickel have similar properties, and their separation is an important research topic in hydrometallurgy of cobalt and nickel. Based on the coordination theory, the extraction of cobalt and nickel was analyzed The principle of separation process and the research direction of extraction and separation of cobalt and nickel were proposed. Keywords: cobalt; nickel; solvent extraction; crystal field theory; molecular orbital theory CLC number: TF804.2 document mark code: A, article number: 1009-2617 (2010) 04-0225-04 Received date: 2009-12-20 Biography: Xiao Chao (1984-), male, Hunan Hengyang, masters degree student, the main research direction is non-ferrous metal metallurgy. At present, cobalt and nickel metallurgical raw materials have been gradually transferred from the former cobalt sulfide nickel ore For cobalt, nickel miscellaneous materials, cobalt nickel oxide ore (including cobalt, nickel laterite ore) and other treatment processes The combination of traditional fire process, matte making and wet separation can be converted to leaching and purification of total moisture Legal process [1-2]. The sources of cobalt and nickel are different. The composition of leaching solution is complicated and precipitate, Ion exchange process is difficult to achieve cobalt, nickel and cobalt, nickel and calcium, magnesium and other impurities Separation of ions. The solvent extraction method has the advantages of good selectivity and high metal recovery Quality, speed, etc, especially according to the difference of ion properties and extract