TiO2纳米管的制备表征及储氢性能研究.doc

TiO2纳米管的制备及储氢性能研究 TiO2纳米管的制备及其储氢性能。①采用阳极氧化法分别在有机和无机电解液中制备TiO2纳米管，通过SEM、XRD、EDS分析表征其表面形貌、组成成份，结果显示有机溶剂中制备的TiO2纳米管管径大约180nm左右；无机溶剂中制备出TiO2纳米管管径在70-100nm左右，管长在300nm以内。②利用脉冲电沉积技术将PbO2沉积在TiO2纳米管上，通过SEM、XRD、EDS对其进行表征。应用循环伏安和充放电实验研究了沉积PbO2前后TiO2纳米管的储氢性能。结果表明，TiO2纳米管具有储氢性能；储氢量为0.01wt%，表面沉积一层PbO2后储氢量有所提高达到0.1wt%。 关键词：TiO2纳米管；阳极氧化；储氢 The study of Preparation and hydrogen-storage capacity of TiO2 nanotubes Abstract Hydrogen becomes a new-type cleaning energy, hydrogen storage has become one of most important subjects currently. The paper mainly study on the preparation and the hydrogen-storage performance of TiO2 nanotube .①The TiO2 nanotube was prepared in the organic and inorganic solution by anodization . Morphology、structure and ingredients was characterized by SEM、XRD、EDS. The results show that the diameter of TiO2 nanotube in the organic solution and inorganic solution is about 180nm and 75nm ,respectively, length is less than 300nm in inorganic solution. ②PbO2 is deposited on the substrate of TiO2 nanotube by the pulse electrodeposition method. And the sample was detected by SEM、XRD、EDS. The hydrogen-storage performance of TiO2 nanotube is discussed through the Cyclic Voltammetry and charge- discharge cycling. The result indicates that TiO2 nanotube possess storage performance; The hydrogen-storage capacities of the TiO2 nanotube was 0.01wt%. TiO2NT/ PbO2 hydrogen-storage capacities was 0.1 wt%. Key words: TiO2 nanotube；anodize；hydrogen-storage 目　　录 摘要 Ⅰ Abstract Ⅱ 第一章 绪论 1 1.1引言 1 1.2储氢材料的研究现状 2 1.2.1储氢合金 2 1.2.2金属有机骨架材料 3 1.2.3金属氢化物储氢材料 4 1.2.4碳质储氢材料 4 1.3 TiO2纳米管 5 1.3.1 TiO2纳米管的制备 6 1.3.2 TiO2纳米管的形成机理 9 1.3.3 TiO2纳米阵列的应用 10 1.4本论文研究思路和研究内容 12 1.4.1 研究思路 12 1.4.2 研究内容 12 第二章 实验部分 13 2.1 试剂与仪器 13 2.2 TiO2纳米管的制备 14 2.2.1钛片的预处理 14 2.2.2电解液的配制 14 2.2.3 TiO2纳米管的制备 14 2.2.4 TiO2纳米管的热处理 15 2.3脉冲电沉积二氧化铅 15 2.4样品的观察与表征 15 2.4.1扫描电镜分析(SEM) 15 2.4.2 X射线衍射分析 16 2.4.3 X射线能谱分析（EDS） 16 2.5电化学储氢性能测试 17 2.5.1循环伏安曲线的测定 17 2.5.2充放电曲线的测定 17 第三章 实验结果与讨论 18 3.1 TiO2纳米管阵列的结构和性能表征 1