bi26mo10o69多孔涂层空气侧改性混合离子导体的制备及其增进透氧性能 preparation and oxygen permeability of bi26mo10o69 porous layer modified ionic-electronic mixed conductor on air side.pdfVIP

Trans. Nonferrous Met. Soc. China 26(2016) 1373− 1378 Preparation and oxygen permeability of Bi26Mo 10O69 porous layer modified ionic-electronic mixed conductor on air side 1 1 1,2 1 Tai-he WANG , Rong LI , Qiang ZHEN , Lin CHENG 1. Nano-Science and Technology Research Center, Shanghai University, Shanghai 200444, China; 2. School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China Received 6 May 2015; accepted 17 November 2015 Abstract: Bi26 Mo 10O69 nanopowder was prepared by hydrothermal method and used as a surface modification material for oxygen separation membrane to enhance oxygen permeability. Thermal decomposition behavior and phase variation of the precursor were investigated by thermal analyzer (TG-DSC) and high-temperature X-ray diffraction (HT-XRD). Bi26 Mo 10O69 porous layer was coated on the air side of BaCo0.7Fe0.2Nb 0.1 O3−δ (BCFN) oxygen permeable membrane by dipping method. In the partial oxidation experiment of coke oven gas (COG), the Bi26 Mo 10O69 -coated BCFN membrane exhibits higher oxygen permeability and CH4 conversion than the uncoated BCFN membrane. When the thickness of BCFN membrane was 1 mm and the COG and air fluxes were 120 and 100 mL/min, the oxygen permeation flux reached 16.48 mL/(min·cm2) at 875 °C, which was 16.96% higher than the uncoated BCFN membrane. Therefore, Bi26 Mo 10O69 porous layer on the air side will be promising modification coating on the oxygen permeability of BCFN membrane. Key words: Bi26 Mo 10O69 ; porous-coating; BaCo