钒钛磁铁矿碳热钠化还原工艺 carbothermal sodium reduction process of vanadium-bearing titanomagnetite.pdfVIP

第51 卷 第 10 期 钢 铁 Vol.51，No. 10，p6-9 2 0 1 6 年 10 月 Iron and Steel October 2016 DOI ：10.13228/j.boyuan.issn0449-749x 钒钛磁铁矿碳热钠化还原工艺 张 俊， 戴晓天， 严定鎏， 齐渊洪 （钢铁研究总院先进钢铁流程及材料国家重点实验室，北京 100081） 摘 要：为了降低钒钛磁铁矿的还原和熔分温度，提高钛与钒的回收率，采取碳热钠化还原法处理钒钛磁铁矿，研 究了钠化剂对钒钛磁铁矿还原以及熔分后钛、钒分布的影响。结果表明，钠化剂能显著改善钒钛磁铁矿的还原性 以及磁选和熔分效果，钠化比为1.2 时，1 100 ℃还原60 min 即可达到90% 以上的金属化率，磁选后铁的收得率达到 92% 以上，铁品位接近80% 。1 450 ℃以上的温度熔分后，铁的收得率高于95% ，钒在铁水中的分配比为91% ，熔分 渣水洗后w(TiO ) 达到56% 。 2 关键词：钒钛磁铁矿；碳热钠化还原；磁选；熔分 文献标志码：A 文章编号：0449-749X （2016 ）10-0006-04 Carbothermal sodium reduction process of vanadium-bearing titanomagnetite ZHANG Jun ， DAI Xiao-tian ，YAN Ding-liu ， QI Yuan-hong （State Key Laboratory of Advanced Steel Processes and Products，Central Iron and Steel Research Institude，Beijing 100081，China） Abstract ：In order to reduce the reduction and smelting-separation temperatures of vanadium-bearing titanomagnetite ， and improve the recovery rate of Ti and V，the carbothermic reduction in combination with sodium-treatment was stud- ied，and the effects of sodium agent on reduction as well as the distribution of Ti and V after smelting-separation were discussed. The sodium agent significantly improves the reducibility，the magnetic separation as well as the smelting-sep- aration performance of vanadium-bearing titanomagnetite，the metallization ratio reached 90% at 1 100 ℃for 60 min when the sodium ratio was 1.2 ，and the fine iron conc