防氚高分子复合材料的制备及其性能 preparation and properties of polymer composite materials for tritium.pdfVIP

第 34 卷 第 3 期 辐射研究与辐射工艺学报 J. Radiat. Res. Radiat. Process. Vol.34, No.3 2016 年 6 月 /fushe/CN/volumn/home.shtml June 2016 防氚高分子复合材料的制备及其性能 游国强 刘占旗 张文宇 郑建国 赵怀璞 蘧艳峰 （中国辐射防护研究院 太原 030006 ） 摘要 利用氯化聚乙烯、聚偏二氯乙烯(Polyvinylidene chloride, PVDC)、高密度聚乙烯等高分子材料复合防 氚材料。采用渗透实验测量氚气渗透率；通过测量断裂强力和剥离力测量力学性能；通过测量浸泡化学试剂 前后的溶失率、断裂强力下降率、剥离力下降率等表征材料的耐化学性能。结果表明，氚气在防氚高分子复 合材料中的渗透率为 3.44×10‒10 3 2 m /(m ∙s)；与PVC 相比，氚气渗透率降低约 70 倍。PVDC 薄膜复合后断裂强 力提高约 20 倍，经纬向断裂强力为 721 N 。防氚高分子复合材料浸泡5 种化学试剂后，最大溶失率为 0.29%、 断裂强力最大下降率为 5.1% ，其力学性能、耐化学性能均满足《防护服装 酸碱类化学品防护服》(GB 24540-2009)等相关标准的要求。 关键词 复合材料，渗透，防氚 中图分类号 TL75+2.3 DOI: 10.11889/j.1000-3436.2016.rrj.34.030305 Preparation and properties of polymer composite materials for tritium YOU Guoqiang LIU Zhanqi ZHANG Wenyu ZHENG Jianguo ZHAO Huaipu QU Yanfeng (China Institute for Radiation Protection, Taiyuan 030006, China) ABSTRACT Composite materials for tritium were determined through the technique of trapping the permeating tritium with water. Testing on mechanical properties such as tensile experiment was performed for both Polyvinylidene chloride (PVDC) films and composite materials. Chemical performance was determined by calculating the dissolved rate in the acid and alkali, breaking strength, loss rate and stripping strength loss rate. The results showed that the gas tritium permeability through the composite materials was 3.44×10‒10 3 2