a minor dihydropyran apocarotenoid from mated cultures of blakeslea trispora一个小dihydropyran apocarotenoid blakeslea交配文化的trispora.pdfVIP

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a minor dihydropyran apocarotenoid from mated cultures of blakeslea trispora一个小dihydropyran apocarotenoid blakeslea交配文化的trispora.pdf

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a minor dihydropyran apocarotenoid from mated cultures of blakeslea trispora一个小dihydropyran apocarotenoid blakeslea交配文化的trispora

Molecules 2012, 17, 12553-12559; doi:10.3390/molecules171112553 OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Communication A Minor Dihydropyran Apocarotenoid from Mated Cultures of Blakeslea trispora Alejandro F. Barrero 1,*, M. Mar Herrador 1, Pilar Artega 1, José-Antonio González 1 and Jesús F. Arteaga 2 1 Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada, Avda. Fuente Nueva, s/n, 18071 Granada, Spain 2 Departamento de Ingeniería Química, Química Fisíca y Químíca Orgánica, Facultad de Ciencias Experimentales, Universidad de Huelva, Campus el Carmen, s/n, 21071 Huelva, Spain * Author to whom correspondence should be addressed; E-Mail: afbarre@ugr.es; Tel./Fax: +34-958-243-318. Received: 8 October 2012; in revised form: 15 October 2012 / Accepted: 22 October 2012 / Published: 24 October 2012 Abstract: The heterocyclic C15 apocarotenoid 1 was isolated from mated cultures of the strains F986 (+) and F921 (−) of Blakeslea trispora . This new compound formed during sexual interaction is a minor constituent of the culture media and its structure was elucidated by spectroscopic data, including 2D-NMR. A plausible biosynthetic pathway involving a double degradation of β-carotene, followed by several oxidations of the resulting monocyclofarnesane C15 fragment is proposed. Keywords: Blakeslea trispora ; apocarotenoid; dihydropyrane; isolation; structural elucidation 1. Introduction Blakeslea trispora (syn. Choanephora tri