a novel biosurfactant, 2-acyloxyethylphosphonate, isolated from waterblooms of aphanizomenon flos-aquae新型生物表面活性剂,2-acyloxyethylphosphonate隔绝waterblooms丝囊藻属的flos-aquae.pdfVIP

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a novel biosurfactant, 2-acyloxyethylphosphonate, isolated from waterblooms of aphanizomenon flos-aquae新型生物表面活性剂,2-acyloxyethylphosphonate隔绝waterblooms丝囊藻属的flos-aquae.pdf

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a novel biosurfactant, 2-acyloxyethylphosphonate, isolated from waterblooms of aphanizomenon flos-aquae新型生物表面活性剂,2-acyloxyethylphosphonate隔绝waterblooms丝囊藻属的flos-aquae

Molecules 2006, 11, 539-548 molecules ISSN 1420-3049 Full Paper A Novel Biosurfactant, 2-Acyloxyethylphosphonate, Isolated from Waterblooms of Aphanizomenon flos-aquae Kunimitsu Kaya 1,*, Louise F. Morrison 2, Geoffrey A. Codd 2,*, James S. Metcalf 2, Tomoharu 3 3 1 Sano , Hiroo Takagi and Takuya Kubo 1 Graduate School of Environmental Studies, Tohoku University, Aoba-ku, Sendai 980-8579, Japan, E-mail: kubo@mail.kankyo.tohoku.ac.jp 2 Division of Environmental and Applied Biology, School of Life Sciences, University of Dundee, Dundee DD1 4HN, UK. E-mails: L.F.morrison@dundee.ac.uk; j.s.metcalf@dundee.ac.uk 3 National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba Ibaraki 305-8506, Japan, E-mails: sanotomo@nies.go.jp; takakiho@nies.go.jp *Authors to whom correspondence should be addressed; E-mail: kaya@mail.kankyo.tohoku.ac.jp, Tel: (+81)-22-795-4506; Fax: (+81)-22-795-4506; E-mail: g.a.codd@dundee.ac.uk Received: 16 June 2006; in revised form: 18 July 2006 / Accepted: 18 July 2006 / Published: 22 July 2006 Abstract: A novel biosurfactant, 2-acyloxyethylphosphonate, was isolated from waterblooms of Aphanizomenon flos-aquae . Its structure was elucidated by chemical degradation and HRFABMS, GC/EI-MS and 1D- and 2D-NMR spectral analyses. The surfactant contained one mole of 2-hydroxyethylphosphonate and one mole of fatty acid, with hexadecanoic acid accounting for 84.1% of the total fatty acid content. The structure was confirmed by synthesis of 2-oleoyloxyethylphosphonate from ethylene oxide,