超声波%2f零价铁协同降解五氯苯酚的的分析研究.pdfVIP

超声波/零价铁协同降解五氯苯酚的研究 摘 要 本文应用超声波/零价铁协同新方法，研究了五氯苯酚及其同 系物的降解特性；考察了在协同体系中溶液初始 pH 值、初始浓 度、零价铁用量、零价铁粒径、通入不同种类气体、反应温度等 影响因素对五氯苯酚降解的影响；重点研究了在协同体系中超声 波与零价铁的协同强化机理，并初步探讨了五氯苯酚在协同体系 中的降解途径与动力学。 研究结果表明：超声波/零价铁协同体系对五氯苯酚的降解具 有明显的协同强化作用，协同体系对五氯苯酚的降解符合一级动 力学反应。在降解过程中，零价铁的用量存在最佳用量，本实验 条件下为 1.5g/L。同时，零价铁粉的粒径越小五氯苯酚的降解效 果越好。 在超声波与零价铁协同降解五氯苯酚的过程中，铁粉没有直 接与五氯苯酚发生化学降解反应，也没有发生吸附降解。·OH 自 由基的氧化作用是五氯苯酚降解的主要作用。在协同体系中起主 导作用是超声波，铁粉的作用强化了超声作用。 关键词：超声波；零价铁；五氯苯酚；协同反应 I 超声波/零价铁协同降解五氯苯酚的研究 Abstract The synergic degradation efficiency of pentachlorophenol by the last innovative technologies of ultrasound cooperated with Zero-Valence Iron was reported. The major affecting factors such as quantity of Zero-Valence Iron, particle diameter of Zero-Valence Iron, initial pH value of solution, initial concentration in ultrasound cooperated with Zero-Valence Iron are studied, at the same time, the kinetics and the synergic mechanism that pentachlorophenol were degraded by ultrasound cooperated with Zero-Valence Iron were studied. The results showed that the pentachlorophenol removal rate by ultrasound cooperated with Zero-Valence Iron is obviously higher than the sum of the removal rates by ultrasound alone and Zero-Valence Iron alone. The synergic effect of ultrasound cooperated with Zero-Valence Iron is significant. The pentachlorophenol degradation follow pseudo-first order