conjugate addition of indoles to α,β-unsaturated ketones using a br？nsted acid ionic liquid as an efficient catalyst共轭添加吲哚α,β-unsaturated酮使用br 望远镜酸离子液体作为一种高效的催化剂.pdfVIP

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conjugate addition of indoles to α,β-unsaturated ketones using a br？nsted acid ionic liquid as an efficient catalyst共轭添加吲哚α,β-unsaturated酮使用br 望远镜酸离子液体作为一种高效的催化剂.pdf

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conjugate addition of indoles to α,β-unsaturated ketones using a br？nsted acid ionic liquid as an efficient catalyst共轭添加吲哚α,β-unsaturated酮使用br 望远镜酸离子液体作为一种高效的催化剂

Molecules 2009, 14, 3222-3228; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Conjugate Addition of Indoles to α,β-Unsaturated Ketones Using a Brønsted Acid Ionic Liquid as an Efficient Catalyst Chuan-Ji Yu and Chen-Jiang Liu * School of Chemistry and Chemical Engineering, Xinjiang University, Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education, 830046 Urumqi, China; E-mail: cjxyycj@126.com (C.-J.Y.) * Author to whom correspondence should be addressed; E-mail: pxylcj@126.com; Tel.: +86-9918581211; Fax: +86-9918582809. Received: 6 July 2009; in revised form: 20 August 2009 / Accepted: 24 August 2009 / Published: 27 August 2009 Abstract: The Brønsted acid ionic liquid [PyN(CH ) SO H][p -CH PhSO ] has been 2 4 3 3 3 reported as an efficient catalyst for the Michael addition reaction of indoles to α,β- unsaturated ketones. Satisfactory results were obtained, with excellent yields and a simple experimental procedure. The catalyst could be recycled and reused up to three times without any noticeable decrease in the catalytic activity. Keywords: Brønsted acid ionic liquid; β-indolylketones; Michael addition Introduction β-indolylketones have received much attention as important building blocks for the synthesis of various natural products and biologically