依数性（Number dependence）.docVIP

依数性（Number dependence） In the second chapter, the dependence of dilute solution Home page Problem analysis Student self test questions Student answer Chapter after Exercises answer Problem analysis [TOP] Case 2-1 is known to have a molar mass of C5H12, M (C5H12) = 72.15 g, mol-1, and a vapor pressure of 77.31 kPa at 20.3 DEG C. A volatile nonvolatile electrolyte 0.0697g was dissolved in 0.891g pentane, and the vapor pressure of the solution was decreased by 2.32 kPa. (1) try to find the constant Raoult in the law of K when the pentane is used as solvent; (2) the molar mass of the solute to be added. Analyze the constants K=, p0MA in Raoults law, and note that P0 is the vapor pressure of the solvent pentane. Solution (1) K = p0MA For pentane, there is K = p0MA = 77.31, kPa * 72.15 g, mol-1? =5578, kPa, G, mol-1 = 5.578, kPa, kg, mol-1 (2) Example 2-2. The coagulation point of a body fluid is -0.50 DEG C, its boiling point and the osmotic pressure of this solution at 0 DEG C (known as water Kf=1.86, K, kg, mol-1, Kb=0.512K, kg, mol-1). The four numerical properties of a dilute solution are analyzed by means of the mass concentration of the solution Therefore, if we know any of the four dependent numbers, we can compute the other three numbers by bB. solution Therefore, the boiling point is 100+0.138 = 100.138 DEG C Osmotic pressure at 0 C = 0.269mol, L-1 * 8.31J, K-1, mol-1 * 273K = 0. 269mol, L-1 * 8.31kPa, L, K-1, mol-1 * 273K = 610 kPa Example 2-3 arrange the following solutions in the order of high to low according to the freezing point of the solution: 0.100mol kg-1 glucose solution II 0.100mol kg-1 NaCl solution The urea solution of 0.100mol, kg-1, 0.100mol, kg-1, the benzene solution of naphthalene A variety of factors should be considered in the analysis: the freezing point of the solvent, the molar freezing point of the solvent, the constant of the decrease, the mass concentration of the solution, the molar concentration, the solute, the electrolyte, or the n