(c5h12n)cu2br3 a piperidinium copper(i) bromide with [cu2br3]？ ladders(c5h12n)cu2br3 piperidinium溴化铜(i)和(cu2br3)梯子.pdfVIP

Crystals 2012, 2, 1434-1440; doi:10.3390/cryst2041434 OPEN ACCESS crystals ISSN 2073-4352 /journal/crystals Article (C H N)Cu Br : A Piperidinium Copper(I) Bromide with 5 12 2 3 − [Cu Br ] Ladders 2 3 Theresa Komm 1, Daniel Biner 1, Antonia Neels 2 and Karl W. Krämer 1,* 1 Department of Chemistry and Biochemistry, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland; E-Mail: daniel.biner@iac.unibe.ch (D.B.) 2 Institute of Microtechnology, CSEM, Rue Jaquet-Droz 1, CH-2002 Neuchâtel, Switzerland; E-Mail: antonia.neels@csem.ch * Author to whom correspondence should be addressed; E-Mail: karl.kraemer@iac.unibe.ch; Tel.: +41-31-631-4248; Fax: +41-31-631-4322. Received: 10 August 2012; in revised form: 3 September 2012 / Accepted: 18 September 2012 / Published: 16 October 2012 Abstract: Piperidinium copper(I) bromide, (C H N)Cu Br , was obtained from a solution 5 12 2 3 of CuBr , piperidine, and HBr in ethanol. At 60 °C ethanol slowly reduces copper(II) to 2 copper(I). Colorless plates of (C H N)Cu Br crystallize in the triclinic space group P-1 5 12 2 3 with lattice parameters of a = 6.2948(10) Å, b = 8.2624(14) Å, c = 10.7612(17) Å, α = 75.964(19)°, β = 89.232(19)°, γ = 84.072(19)°, and Z = 2 at 173 K. [CuBr4] tetrahedra share edges and form [Cu