a novel soluble tin(iv) porphyrin modified single-walled carbon nanotube nanohybrid with light harvesting properties一种新型可溶性锡(iv)卟啉修饰单壁碳纳米管nanohybrid与光属性.pdfVIP
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a novel soluble tin(iv) porphyrin modified single-walled carbon nanotube nanohybrid with light harvesting properties一种新型可溶性锡(iv)卟啉修饰单壁碳纳米管nanohybrid与光属性
Int. J. Mol. Sci. 2008, 9, 45-55
International Journal of
Molecular Sciences
ISSN 1422-0067
© 2008 by MDPI
/ijms/
Full Research Paper
A Novel Soluble Tin(IV) Porphyrin Modified Single-Walled
Carbon Nanotube Nanohybrid With Light Harvesting
Properties
1 1 2 2 1 1
Dong-Mei Ren , Zhen Guo , Feng Du , Zun-Feng Liu , Zai-Chun Zhou , Xiu-Ying Shi ,
Yong-Sheng Chen 2,* and Jian-Yu Zheng1,*
1 State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin
300071, PR China
2 Center for Nanoscale Science and Technology and Key Laboratory for Functional Polymer
Materials, College of Chemistry, Nankai University, Tianjin 300071, PR China
* Author to whom correspondence should be addressed; Tel: +86 22 2350 5572; Fax: +86 22 2350
5572; E-mail: jyzheng@ (J. Z.) and yschen99@ (Y. C.)
Received: 24 October 2007; in revised form: 12 December 2007 / Accepted: 4 January 2008 /
Published: 21 January 2008
Abstract: A dihydroxotin(IV) porphyrin functionalized single-walled carbon nanotubes
(SWNTs) nanohybrid is obtained. Solubility of the nanohybrid in organic solvents is
determined by UV-Vis-NIR absorption spectroscopy. Electron absorption and fluorescence
spectra investigations demonstrate that efficient electron transfer occurs within the
nanohybrid at the photoexcited state
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