ammonia uptake and release in the mnx2–nh3 (x = cl, br) systems and structure of the mn(nh3)nx2 (n = 6, 2) ammines氨的吸收和释放mnx2-nh3(x = cl,br)系统和结构的锰(nh3)nx2(n = 6,2)氨合物.pdfVIP
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ammonia uptake and release in the mnx2–nh3 (x = cl, br) systems and structure of the mn(nh3)nx2 (n = 6, 2) ammines氨的吸收和释放mnx2-nh3(x = cl,br)系统和结构的锰(nh3)nx2(n = 6,2)氨合物
Crystals 2012, 2, 193-212; doi:10.3390/cryst2020193
OPEN ACCESS
crystals
ISSN 2073-4352
/journal/crystals
Article
Ammonia Uptake and Release in the MnX –NH (X = Cl, Br)
2 3
Systems and Structure of the Mn(NH ) X (n = 6, 2) Ammines
3 n 2
Hazel Reardon, James M. Hanlon, Michael Grant, Imogen Fullbrook and Duncan H. Gregory *
WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, Glasgow G12 8QQ,
UK; E-Mails: hazelr@chem.gla.ac.uk (H.R.); jamhan@chem.gla.ac.u k (J.M.H.);
michaelgrant262@ (M.G.); 0706652f@student.gla.ac.uk (I.F.)
* Author to whom correspondence should be addressed; E-Mail: duncan.gregory@glasgow.ac.uk;
Tel.: +44-141-330-6438; Fax: +44-141-330-4888.
Received: 21 February 2012; in revised form: 18 March 2012 / Accepted: 30 March 2012 /
Published: 10 April 2012
Abstract: Hexa-ammine complexes, Mn(NH ) X (X = Cl, Br), have been synthesized by
3 6 2
ammoniation of the corresponding transition metal halide and characterized by Powder
X-ray diffraction (PXRD) and Raman spectroscopy. The hexa-ammine complexes are
isostructural (Cubic, Fm-3m, Z = 4; a = 10.2742(6) Å and 10.527(1) Å for X = Cl, Br
respectively). Temperature programmed desorption (TPD)
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