锂离子电池-背景介绍与研究进展.ppt

XXXX;Recent developments in cathode materials for lithium ion batteries;1. Introduction;2. Cathode materials;3. Cathode performance;Fig. 4. Plateau voltage and capacity for Li(Ni1/3Mn1/3Co1/3)O2 ,LiCoO2, LiFePO4 , and LiMn2O4 with a charging voltage of 4.3V and discharge current of 1C.;Fig. 6. Discharge capacity of LiCoO2 as a function of discharge rate.;Fig. 8. Discharge capacity of LiFePO4 as a function of discharge rate.;Figs. 10~12. Capacity after 1st/50th cycle and percent change in capacity after 50 cycles for LiFePO4 LiCoO2 Li(Ni,Mn,Co)O2 cathodes.;4. Composite cathodes;5. Effect of doping; High voltages, high discharge current, good capacities are required. ;Niobium doped lithium titanate as a high rate anode material for Li-ion batteries;1. Introduction;Solution;2. Experimental;3. Results and discussion;Fig. 2. SEM pictures of (a) Li4Ti5O12 and (b) Li4Ti4.95Nb0.05O12.;Fig. 3. EDS element mapping of the Li4Ti4.95Nb0.05O12.;Fig. 4. Initial discharge–charge curves of (a) Li4Ti5O12 and (b) Li4Ti4.95Nb0.05O12 at different rates (0.5 C, 1 C, 2 C, 10 C, 20 C, 40 C).;Fig. 5. Cyclic performance of the Li4Ti5O12 and the Li4Ti4.95Nb0.05O12 at (a) 1 C and(b) 10 C.;Fig. 6. Discharge–charge capacity performance and coulombic efficiency of theLi4Ti4.95Nb0.05O12 electrode. Discharge current: 0.5 C. Charge current: (A) 0.5 C, (B)1 C, (C) 2 C, (D) 5 C, (E) 10 C, (F) 20 C and (G) 0.2 C.;Fig. 7. Cyclic voltammograms of the Li4Ti5O12 and the Li4Ti4.95Nb0.05O12, with scan rate of 0.5mV·s?1.;Fig. 8. (a) Electrochemical impedance spectra of the Li4Ti5O12 and the Li4Ti4.95Nb0.05O12 discharged to the depth of 50% followed by two cycles; (b)equivalent circuit for Fig. 8 (a) Rs: electrolyte resistance; Rct: charge-transfer resistance;CPE: double-layer capacitance and passivation film capacitance; Zw:Warburg impedance.;4. Conclusions;thanks