不同时间对钛表面微弧氧化处理后及瓷结合强度影响.docVIP

不同时间对钛表面微弧氧化处理后及瓷结合强度影响 　作者：李健学，张玉梅，憨勇，刘啸晨，于凡 【关键词】 微弧氧化；时间；结合强度;肽 　　Effects of microarc oxidation time on bonding strength of titanium to porcelain 【Abstract】 AIM：To study the effects of time length of microarc oxidation (MAO) on the titaniumceramic bonding strength. METHODS： Titanium samples were treated with MAO in a Na2SiO3 electrolytic solution with duty cycle 0.04, frequency 500 Hz, and voltage 300 V. According to the different oxidation time, experimental groups consisted of 3, 6, 10 min groups. The nonMAO samples were used as a control group. The surface of the samples was observed by scanning electron microscope (SEM). The samples were bonded to porcelain. The bonding strength of the samples was measured by a threepoint bending test. RESULTS： The bonding strength (MPa) of the samples to porcelain in 3, 6, 10 min groups and control group was 56.4±0.8, 40.4±2.3，36.0±3.0，32.2±1.9. The longer the oxidation time was, the rougher the surface was, the larger the pore diameter was and the fewer the pore was. The thickness of oxidized layer was increased from 5 μm to 12 μm, but the bonding strength of titaniumporcelain was decreased, respectively (3min group vs 6min and 10min group, Plt;0.01; 6min group vs 10min group, P＞0.05). The bonding strength of the MAO groups were higher than that of the nonMAO group (Plt;0.01). CONCLUSION： The MAO on titanium is favorable to the titanium ceramic bonding strength and the different oxidation time has a different effect on the titaniumceramic bonding strength. 【Keywords】 microarc oxidation；time；bonding strength; titanium 【摘要】 目的：观察钛试样在微弧氧化处理过程中于不同氧化时间形成的氧化膜对钛瓷结合强度的影响. 方法: 电解液由去离子水和Na2SiO3溶液组成，占空比和频率分别为0.04,500 Hz，电压300 V,根据时间不同分为3组，分别为3, 6, 10 min组. 对钛试样表面进行处理，将未行微弧氧化处理的钛试样作为对照组. 扫描电镜观察膜表面形貌；对不同组别试件进行瓷粉烧结;采用三点弯曲试验测量钛与瓷的结合强度. 结果：3, 6, 10 min组和未行微弧氧化组与瓷的结度分别是56.4±0.8，40.4±2.3，36.0±3.0，32.2±1.9. 随着氧化时间的延长,试件表面变化较大,微孔直径增大,微孔数量明显减少，表面变得粗糙，氧化层膜的厚度也随之增加，从5 μm左右增加到12 μm. 随时间的延长,钛与瓷的结合强度逐渐降低，结合强度在3 min组明显高于6，10 min组(P＜0.01)，6，10 mi