ICPAES法测定皮革中七种重金属元素.pdfVIP

第29 卷 第3 期 皮 革 与 化 工 Vol. 29 No.3 2012 年6 月 LEATHER AND CHEMICALS Jun. 2012 技术交流 ICP- AES 法测定皮革中 七种重金属元素 钟锋 （安徽大学水基高分子研究中心，合肥安科精细化工有限公司, 安徽合肥230088） 摘要: 建立电感耦合等离子体原子发射光谱法(ICP- AES)测定皮革中七种重金属元素含量的方法。采用微波消 解处理样品，并考察了不同元素间相互干扰，采用ICP- AES 同时测定七种重金属元素。对所测定元素的相对标 准偏差（RSD）均小于4%, 回收率在95%～104%之间,结果可信度高。 关键词: 电感耦合等离子体原子发射光谱法；皮革；重金属；微波消解 中图分类号:O657.31 文献标识码:A 文章编号:1674- 0939(2012)03- 0029- 03 Determination of 7 Heavy Metal Elements in Leather by ICP-AES ZHONG Feng （Research Center of Waterborne Polymers of Anhui University，Hefei Anke Fine Chemicals Co. Ltd. ，Hefei 230088, China） Abstract: To establish an ICP- AES method for the determination of multiplex elements in leather, the samples were digested by microwave and 7 elements were assayed by ICP- AES. The mutual interference of the 7 elements and the treatment of the sample were studied in details. For all of the analyzed elements the relative standard deviations (RSD) are less than 4% and the recoveries of most elements were in the range of 95%~104%. This method used in this study was simple, accurate and fast in detecting 7 elements in leather, and hence could be used as an effective measurement of multiplex elements for its quality control. Key words: ICP- AES；leather ；heavy metal elements; microwave acid digestion 重金属对人体的累积毒性相当严重，铅、镉等重 皮革中重金属成分在生态系统中也会造成循环积 金属元素，对人体健康有害。钴能够导致皮肤和心脏 累，对自然环境构成威胁。皮革样品中的重金属元素 病；少量的镉和铅进入机体，即可通过生物放大作用 [3- 6] 检测方法较多 ，由于微波消解样品及电感耦合等 和生物沉积，对肾、肺、肝、脑