多壁碳纳米管的改性.pdfVIP

DOI :10.14159/ki.0441-3776.2005.08.009 ·618 · 　2005 8　　　　　　　　　　http: CVDFenton ＊ 李伟　成荣明 　徐学诚　陈奕卫　孙明礼　何为凡 (　　200062) 　　, , Fenton ·OH CVD 。 (FT-I ), 、。 , , 、, CVD Fenton 。 , ·OH 。 　　Fenton 　·OH　 FentonOxidationModification ofMulti-walled CarbonNanotubesPrepared inDifferent Conditionsby CVDMethod ＊ Li Wei, Cheng ongming , Xu Xuecheng, Chen Yiwei, Sun Mingli, He Weifan (Center of Functional Nanomaterials and Devices, East China Normal University, Shanghai 200062) Abstract　After purification pretreatment by heating in air and in dilute HNO , in the same experimental 3 conditionstwo kinds of multi-walled carbon nanotubes (MWNTs)were treated with Fenton s reagents, which were synthesized in different preparation conditions by chemical vapor deposition (CVD)method.The results of FT-I spectra indicated that the oxygen-containing functional groups such as hydroxyl groups, carbonyl groups and carboxyl groups could be brought into two kinds of MWNTs after Fenton oxidation modification treatment.In addition, the properties such as graphitization degree, defects′content and antioxidation ability are also different for the different preparation conditions.So the preparation conditions of MWNTs could affect intensively the results of Fenton oxidation modification.Finally, we discussed the possible mechanisms of reaction betweenhydroxyl radical and MWNTs by FT- I spectral changes before and after Fenton modification treatments were discussed.The possible mechanisms indicated that the existence of oxygen-containing functional groups could be viewed as outcome of attacks of hydroxyl radical (·OH)wi