observation of different catalytic activity of various 1-olefins during ethylene1-olefin copolymerization with homogeneous metallocene catalysts期间观察不同催化活性的各种1-olefins ethylene1-olefin共聚与均相茂金属催化剂.pdfVIP

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observation of different catalytic activity of various 1-olefins during ethylene1-olefin copolymerization with homogeneous metallocene catalysts期间观察不同催化活性的各种1-olefins ethylene1-olefin共聚与均相茂金属催化剂.pdf

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observation of different catalytic activity of various 1-olefins during ethylene1-olefin copolymerization with homogeneous metallocene catalysts期间观察不同催化活性的各种1-olefins ethylene1-olefin共聚与均相茂金属催化剂

Molecules 2011, 16, 373-383; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene/1-Olefin Copolymerization with Homogeneous Metallocene Catalysts Mingkwan Wannaborworn, Piyasan Praserthdam and Bunjerd Jongsomjit * Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand * Author to whom correspondence should be addressed; E-Mail: bunjerd.j@chula.ac.th; Tel.: +66 2 2186869; Fax: +66 2 2186877. Received: 18 November 2010; in revised form: 28 December 2010 / Accepted: 5 January 2011 / Published: 7 January 2011 Abstract: This research aimed to investigate the copolymerization of ethylene and various 1-olefins. The comonomer lengths were varied from 1-hexene ( 1-C ) up to 1-octadecene ( 1- 6 C18) in order to study the effect of comonomer chain length on the activity and properties of the polymer in the metallocene/MAO catalyst system. The results indicated that two distinct cases can be described for the effect of 1-olefin chain length on the activity. Considering the short chain length comonomers, such as 1-hexene, 1-octene and 1-decene, it is obvious that the polymerization activity decreased when the length of comonomer was higher, which is probably due to increa