observation of t-2 toxin and ht-2 toxin glucosides from fusarium sporotrichioides by liquid chromatography coupled to tandem mass spectrometry (lc-msms)观察2毒素和青灵毒素从镰刀菌素糖甙sporotrichioides通过液相色谱耦合串联质谱(lc-msms).pdfVIP

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observation of t-2 toxin and ht-2 toxin glucosides from fusarium sporotrichioides by liquid chromatography coupled to tandem mass spectrometry (lc-msms)观察2毒素和青灵毒素从镰刀菌素糖甙sporotrichioides通过液相色谱耦合串联质谱(lc-msms).pdf

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observation of t-2 toxin and ht-2 toxin glucosides from fusarium sporotrichioides by liquid chromatography coupled to tandem mass spectrometry (lc-msms)观察2毒素和青灵毒素从镰刀菌素糖甙sporotrichioides通过液相色谱耦合串联质谱(lc-msms)

Toxins 2011, 3, 1554-1568; doi:10.3390/toxins3121554 OPEN ACCESS toxins ISSN 2072-6651 /journal/toxins Article Observation of T-2 Toxin and HT-2 Toxin Glucosides from Fusarium sporotrichioides by Liquid Chromatography Coupled to Tandem Mass Spectrometry (LC-MS/MS) Mark Busman *, Stephen M. Poling and Chris M. Maragos U.S. Agricultural Research Service, National Center for Agricultural Utilization Department of Agriculture Research, Peoria, IL 61604, USA; E-Mails: Stephen.Poling@ (S.M.P.); Chris.Maragos@ (C.M.M.) * Author to whom correspondence should be addressed; E-Mail: Mark.Busman@; Tel.: +1-309-681-6241; Fax: +1-309-681-6293. Received: 24 November 2011; in revised form: 14 December 2011 / Accepted: 19 December 2011 / Published: 20 December 2011 Abstract: The trichothecenes produced by solid and liquid cultures of Fusarium sporotrichioides were evaluated with high performance liquid chromatography—tandem mass spectrometry (LC-MS/MS). Along with the expected T-2 toxin HT-2 toxin and neosolaniol, two additional compounds were detected, which had ions 162 m/z higher than those in the mass spectra of T-2 toxin or HT-2 toxin. Fragmentation behavior of these two compounds was similar to that of T-2 toxin and HT-2 toxin. Based on LC-MS/MS behavior, it is proposed that the two compounds are T-2 toxin 3-O-glucoside and HT-2 toxin 3-O-glucoside. Production of the two glucosides was measured in kernels from wheat and oat inoculated with