oxidation of phenol by hydrogen peroxide catalyzed by metal-containing poly(amidoxime) grafted starch由过氧化氢催化氧化酚含金属聚(amidoxime)接枝淀粉.pdfVIP

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oxidation of phenol by hydrogen peroxide catalyzed by metal-containing poly(amidoxime) grafted starch由过氧化氢催化氧化酚含金属聚(amidoxime)接枝淀粉.pdf

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oxidation of phenol by hydrogen peroxide catalyzed by metal-containing poly(amidoxime) grafted starch由过氧化氢催化氧化酚含金属聚(amidoxime)接枝淀粉

Molecules 2011, 16, 9900-9911; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Communication Oxidation of Phenol by Hydrogen Peroxide Catalyzed by Metal-Containing Poly(amidoxime) Grafted Starch Hany El-Hamshary 1,2,*, Mohamed H. El-Newehy 1,2 and Salem S. Al-Deyab 1 1 Petrochemical Research Chair, Department of Chemistry, College of Science, King Saud University, B.O. Box 2455, Riyadh 11451, Saudi Arabia 2 Department of Chemistry, Faculty of Science, Tanta University, Tanta 31527, Egypt * Author to whom correspondence should be addressed; E-Mail: helhamshary@.sa; or hany_elhamshary@.eg; Tel.: +966-01-469-6491; Fax: +966-01-467-5992. Received: 11 October 2011; in revised form: 23 November 2011 / Accepted: 24 November 2011 / Published: 29 November 2011 Abstract: Polyamidoxime chelating resin was obtained from polyacrylonitrile (PAN) grafted starch. The nitrile groups of the starch-grafted polyacrylonitrile (St-g-PAN) were converted into amidoximes by reaction with hydroxylamine under basic conditions. The synthesized graft copolymer and polyamidoxime were characterized by FTIR, TGA and elemental microanalysis. Metal chelation of the polyamidoxime resin with iron, copper and zinc has been studied. The produced metal-polyamidoxime polymer complexes were used as catalysts for the oxidation of phenol using H O as oxidizing agent. The oxidation of 2 2 phenol depends