poly(imide)organically-modified montmorillonite nanocomposite as a potential membrane for alkaline fuel cells聚酰亚胺有机蒙脱土纳米复合材料作为一个潜在的碱性燃料电池的膜.pdfVIP

poly(imide)organically-modified montmorillonite nanocomposite as a potential membrane for alkaline fuel cells聚酰亚胺有机蒙脱土纳米复合材料作为一个潜在的碱性燃料电池的膜.pdf

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poly(imide)organically-modified montmorillonite nanocomposite as a potential membrane for alkaline fuel cells聚酰亚胺有机蒙脱土纳米复合材料作为一个潜在的碱性燃料电池的膜

Membranes 2012, 2, 430-439; doi:10.3390/membranes2030430 OPEN ACCESS membranes ISSN 2077-0375 /journal/membranes Article Poly(imide)/Organically-Modified Montmorillonite Nanocomposite as a Potential Membrane for Alkaline Fuel Cells Liliane C. Battirola, Luiz H. S. Gasparotto *, Ubirajara P. Rodrigues-Filho and Germano Tremiliosi-Filho Instituto de Química de São Carlos, Universidade de São Paulo, São Carlos 13560-970, São Paulo, Brazil; E-Mails: lcbattirola@iqsc.usp.br (L.C.B.); uprf@iqsc.usp.br (U.P.R.F.); germano@iqsc.usp.br (G.T.F.) * Author to whom correspondence should be addressed; E-Mail: lhgasparotto@iqsc.usp.br; Tel.: +55-16 Fax: +55-16 Received: 7 May 2012; in revised form: 19 June 2012 / Accepted: 4 July 2012 / Published: 18 July 2012 Abstract: In this work we evaluated the potentiality of a poly(imide) (PI)/organically-modified montmorillonite (O-MMT) nanocomposite membrane for the use in alkaline fuel cells. Both X-ray diffraction and scanning electron microscopy revealed a good dispersion of O-MMT into the PI matrix and preservation of the O-MMT layered structure. When compared to the pure PI, the addition of O-MMT improved thermal stability and markedly increased the capability of absorbing electrolyte and ionic conductivity of the composite. The results show that the PI/O-MMT nanocomposite is a promising candidate for alkaline fuel cell applications. Keywords: clay-modified poly(imide); alkaline fuel cell; membranes 1. I

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