poly(imide)organically-modified montmorillonite nanocomposite as a potential membrane for alkaline fuel cells聚酰亚胺有机蒙脱土纳米复合材料作为一个潜在的碱性燃料电池的膜.pdfVIP
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poly(imide)organically-modified montmorillonite nanocomposite as a potential membrane for alkaline fuel cells聚酰亚胺有机蒙脱土纳米复合材料作为一个潜在的碱性燃料电池的膜
Membranes 2012, 2, 430-439; doi:10.3390/membranes2030430
OPEN ACCESS
membranes
ISSN 2077-0375
/journal/membranes
Article
Poly(imide)/Organically-Modified Montmorillonite
Nanocomposite as a Potential Membrane for Alkaline
Fuel Cells
Liliane C. Battirola, Luiz H. S. Gasparotto *, Ubirajara P. Rodrigues-Filho and
Germano Tremiliosi-Filho
Instituto de Química de São Carlos, Universidade de São Paulo, São Carlos 13560-970, São Paulo,
Brazil; E-Mails: lcbattirola@iqsc.usp.br (L.C.B.); uprf@iqsc.usp.br (U.P.R.F.);
germano@iqsc.usp.br (G.T.F.)
* Author to whom correspondence should be addressed; E-Mail: lhgasparotto@iqsc.usp.br;
Tel.: +55-16 Fax: +55-16
Received: 7 May 2012; in revised form: 19 June 2012 / Accepted: 4 July 2012 /
Published: 18 July 2012
Abstract: In this work we evaluated the potentiality of a poly(imide)
(PI)/organically-modified montmorillonite (O-MMT) nanocomposite membrane for the use
in alkaline fuel cells. Both X-ray diffraction and scanning electron microscopy revealed a
good dispersion of O-MMT into the PI matrix and preservation of the O-MMT layered
structure. When compared to the pure PI, the addition of O-MMT improved thermal
stability and markedly increased the capability of absorbing electrolyte and ionic
conductivity of the composite. The results show that the PI/O-MMT nanocomposite is a
promising candidate for alkaline fuel cell applications.
Keywords: clay-modified poly(imide); alkaline fuel cell; membranes
1. I
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