preparation of benzothiazole-substituted carbosilane dendrimers up to the 7th generation制备benzothiazole-substituted carbosilane第七代树枝状分子.pdfVIP

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preparation of benzothiazole-substituted carbosilane dendrimers up to the 7th generation制备benzothiazole-substituted carbosilane第七代树枝状分子.pdf

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preparation of benzothiazole-substituted carbosilane dendrimers up to the 7th generation制备benzothiazole-substituted carbosilane第七代树枝状分子

Molecules 2009, 14, 1605-1613; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Preparation of Benzothiazole-Substituted Carbosilane Dendrimers up to the 7th Generation Chungkyun Kim * and Hyojeong Kim Department of Chemistry, Dong-A University, Busan 604-714, Korea; E mail: hjkim@upchem.co.kr (H.K.) * Author to whom correspondence should be addressed; E-mail: ckkim@dau.ac.kr. Received: 18 March 2009; in revised form: 13 April 2009 / Accepted: 20 April 2009 / Published: 21 April 2009 Abstract: Carbosilane dendrimers with 2-(2-phenyloxy)benzothiazole groups on the periphery were prepared from the 1st to the 7th generation. All dendrimers were characterized by 1H- and 13C-NMR, elemental analysis, MALDI TOF MS, GPC, and PL (photoluminescence) spectroscopy. Characteristic PDI (Polydisperse Index) values of the peaks corresponding to the respective dendrimers in the GPC data is in very narrow range st of 1.00~1.04. All PL spectra show a blue-shift increasing with generation from the 1 to the th 7 . Keywords: Dendrimer; Carbosilane; PL; GPC; Silicone. 1. Introduction Confirmation of dendrimer isomolecularity has been a controversi