qcm-arrays for sensing terpenes in fresh and dried herbs via bio-mimetic mip layersqcm-arrays通过仿生传感萜烯的新鲜和干草药mip层.pdfVIP

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qcm-arrays for sensing terpenes in fresh and dried herbs via bio-mimetic mip layersqcm-arrays通过仿生传感萜烯的新鲜和干草药mip层.pdf

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qcm-arrays for sensing terpenes in fresh and dried herbs via bio-mimetic mip layersqcm-arrays通过仿生传感萜烯的新鲜和干草药mip层

Sensors 2010, 10, 6361-6376; doi:10.3390/s100706361 OPEN ACCESS sensors ISSN 1424-8220 /journal/sensors Article QCM-Arrays for Sensing Terpenes in Fresh and Dried Herbs via Bio-Mimetic MIP Layers † Naseer Iqbal, Ghulam Mustafa, Abdul Rehman, Alexander Biedermann, Bita Najafi, Peter A. Lieberzeit and Franz L. Dickert * Department of Analytical Chemistry, University of Vienna, Waehringer Strasse 38, A-1090 Vienna, Austria; E-Mails: naseer.iqbal@univie.ac.at (N.I.); ghulam.mustafa@univie.ac.at (G.M.); abduhl.rehman@univie.ac.at (A.R.); alexander.biedermann@univie.ac.at (A.B.); bita.najafi@univie.ac.at (B.N.); peter.lieberzeit@univie.ac.at (P.A.L.) * Author to whom correspondence should be addressed; E-Mail: franz.dickert@univie.ac.at; Tel.: +43-1-4277-52317, Fax: +43-1-4277-9523. † Dedicated to Professor Wolfhard Wegscheider on the occasion of his 60th birthday. Received: 10 May 2010; in revised form: 25 May 2010 / Accepted: 15 June 2010 / Published: 28 June 2010 Abstract: A piezoelectric 10 MHz multichannel quartz crystal microbalance (MQCM), coated with six molecularly imprinted polystyrene artificial recognition membranes have been developed for selective quantification of terpenes emanated from fresh and dried Lamiaceae family species, i.e., rosemary (Rosmarinus Officinalis L.), basil (Ocimum Basilicum) and sage (Salvia Officinalis). Optimal e-nose parameters, such as layer heights (1–6 KHz), sensitivity 20 ppm of analytes, selectivity at 50 ppm of terpenes, repeatability