reactions of substituted furan-2-carboxaldehydes and furo[b]pyrrole type aldehydes with benzothiazolium salts反应代替furan-2-carboxaldehydes和furo[b]吡咯类醛与benzothiazolium盐.pdfVIP

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reactions of substituted furan-2-carboxaldehydes and furo[b]pyrrole type aldehydes with benzothiazolium salts反应代替furan-2-carboxaldehydes和furo[b]吡咯类醛与benzothiazolium盐.pdf

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reactions of substituted furan-2-carboxaldehydes and furo[b]pyrrole type aldehydes with benzothiazolium salts反应代替furan-2-carboxaldehydes和furo[b]吡咯类醛与benzothiazolium盐

Molecules 2004, 9, 241-255 molecules ISSN 1420-3049 Reactions of Substituted Furan-2-carboxaldehydes and Furo[b]pyrrole Type Aldehydes with Benzothiazolium Salts Zita Puterová 1, Alžbeta Krutošíková 1,*, Antonín Lyčka 2 and Tatiana Ďurčeková 1 1 Department of Chemistry, Faculty of Natural Sciences, University of St. Cyril and Methodius in Trnava, SK-917 01 Trnava, Slovak Republic, Tel. (+421) 3 5565 372, Fax (+421) 3 5565 185. 2 Research Institute for Organic Syntheses, Rybitvi 296, CZ-532 18 Pardubice 20, Czech Republic. *Author to whom correspondence should be addressed; e-mail: krutosik@ucm.sk Received: 18 February 2004 / Accepted: 23 March 2004 / Published: 31 March 2004 Abstract: A series of new push-pull compounds were synthesised by reaction of 5-aryl- furan-2-carboxaldehydes and furo[b]pyrrole type aldehydes with benzothiazolium salts. These new condensation products represent highly conjugated systems that have potential biological activity. The reaction of furo[b]pyrrole type aldehydes with benzothiazolium salts give potential precursors of cyanine dyes. Keywords: 5-Arylfuran-2-carboxaldehydes; 2-formylfuro[3,2-b]pyrrole-5-carboxylates; 2-formylfuro[2,3-b]pyrrole-5-carboxylate; benzothiazolium salts, 1H- and 13C-NMR spectra. Introduction Many compounds containing the benzothiazole moiety are reported to be biologically active and good structure-activity relations have been found using QSAR studies [1,2]. High antimicrobial activity of benzothiazolium salts has been reported for systems bearing electro