reduction of nitrogen compounds in oceanic basement and its implications for hcn formation and abiotic organic synthesis减少含氮化合物在地下室海洋及其对hcn形成和非生物有机合成的影响.pdfVIP

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reduction of nitrogen compounds in oceanic basement and its implications for hcn formation and abiotic organic synthesis减少含氮化合物在地下室海洋及其对hcn形成和非生物有机合成的影响.pdf

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reduction of nitrogen compounds in oceanic basement and its implications for hcn formation and abiotic organic synthesis减少含氮化合物在地下室海洋及其对hcn形成和非生物有机合成的影响

Geochemical Transactions BioMed Central Review Open Access Reduction of nitrogen compounds in oceanic basement and its implications for HCN formation and abiotic organic synthesis Nils G Holm* and Anna Neubeck Address: Department of Geology and Geochemistry, Stockholm University, Stockholm, Sweden Email: Nils G Holm* - nils.holm@geo.su.se; Anna Neubeck - anna.neubeck@geo.su.se * Corresponding author Published: 22 October 2009 Received: 7 April 2009 Accepted: 22 October 2009 Geochemical Transactions 2009, 10:9 doi:10.1186/1467-4866-10-9 This article is available from: /content/10/1/9 © 2009 Holm and Neubeck; licensee BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Abstract Hydrogen cyanide is an excellent organic reagent and is central to most of the reaction pathways leading to abiotic formation of simple organic compounds containing nitrogen, such as amino acids, purines and pyrimidines. Reduced carbon and nitrogen precursor compounds for the synthesis of HCN may be formed under off-axis hydrothermal conditions in oceanic lithosphere in the presence of native Fe and Ni and are adsorbed on authigenic layer silicates and zeolites. The native metals as well as the molecular hydrogen reducing CO to CO/CH and NO -/NO - to NH /NH + are a