rheological behaviors of polyacrylonitrile1-butyl-3- methylimidazolium chloride concentrated solutions流变行为polyacrylonitrile1-butyl-3 -氯化methylimidazolium集中解决方案.pdfVIP

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rheological behaviors of polyacrylonitrile1-butyl-3- methylimidazolium chloride concentrated solutions流变行为polyacrylonitrile1-butyl-3 -氯化methylimidazolium集中解决方案.pdf

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rheological behaviors of polyacrylonitrile1-butyl-3- methylimidazolium chloride concentrated solutions流变行为polyacrylonitrile1-butyl-3 -氯化methylimidazolium集中解决方案

Int. J. Mol. Sci. 2007, 8, 180-188 International Journal of Molecular Sciences ISSN 1422-0067 © 2007 by MDPI /ijms/ Rheological Behaviors of Polyacrylonitrile/1-Butyl-3- Methylimidazolium Chloride Concentrated Solutions * Weiwei Liu, Lingyan Cheng, Hongyan Zhang, Yumei Zhang, Huaping Wang and Mingfang Yu 1 State Key Laboratory for Modification of Fibers Materials, Donghua University, Shanghai 200051, People’s Republic of China * Author to whom correspondence should be addressed. E-Mail: towardsun@ Received: 30 August 2006; in revised form: 8 February 2007 / Accepted: 12 February 2007 / Published: 7 March 2007 Abstract: One of the room temperature ionic liquids (RTILs), 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) was chosen to prepare the concentrated solutions of Polyacrylonitrile (PAN). The rheological behaviors of the solutions were measured with rotational rheometry under different conditions, including temperatures, concentration, and molecular weight of PAN. The solutions exhibited shear-thinning behaviors, similar to that of PAN/DMF solutions. The viscosities decreased with the increasing of shear rates. However, the viscosity decreased sharply at high shear rates when the concentration was up to 16wt%. The dependence of the viscosity on temperature was analyzed through the determination of the