ru11lu20, a new intermetallic compound with eight- to ten-coordinate ruthenium atomsru11lu20,一个新的金属互化物与8 - ten-coordinate钌原子.pdfVIP

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ru11lu20, a new intermetallic compound with eight- to ten-coordinate ruthenium atomsru11lu20,一个新的金属互化物与8 - ten-coordinate钌原子.pdf

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ru11lu20, a new intermetallic compound with eight- to ten-coordinate ruthenium atomsru11lu20,一个新的金属互化物与8 - ten-coordinate钌原子

Crystals 2012, 2, 704-709; doi:10.3390/cryst2020704 OPEN ACCESS crystals ISSN 2073-4352 /journal/crystals Communication Ru11Lu20, a New Intermetallic Compound with Eight- to Ten-Coordinate Ruthenium Atoms Sina Zimmermann, Ingo Pantenburg and Gerd Meyer * Department für Chemie, Universität zu Köln, Greinstraße 6, D-50939 Köln, Germany; E-Mails: sina.babai@ (S.Z.); ac118@uni-koeln.de (I.P.) * Author to whom correspondence should be addressed; E-Mail: gerd.meyer@uni-koeln.de; Tel.: +49-221-470-3262; Fax: +49-221-470-5083. Received: 14 May 2012; in revised form: 11 June 2012 / Accepted: 12 June 2012 / Published: 20 June 2012 Abstract: The new intermetallic compound Ru11Lu20 was obtained as black single crystals during an attempted comproportionation reaction of lutetium(III) chloride, LuCl , with 3 metallic lutetium in the presence of ruthenium metal at 950 °C. Ru11Lu20 crystallizes with the trigonal space group R-3, Z = 6, a = 1255.1(1), c = 2973.0(4) pm, R 1 for all data: 0.0380. Ruthenium atoms center eight-, nine- and ten-vertex polyhedra of lutetium atoms which are connected in a complicated manner to a three-dimensional network. Keywords: ruthenium; lutetium; polar intermetallic; crystal structure 1. Introduction A plethora of reduced rare-earth metal halides at the borderline between metal and salt have been obtained within the last decades [1–12]. These contain cluster comp