structural and electrical properties of the τ-(p-s,s-dmedt-ttf)2 (aucl2) (aucl2)y compound with (y ≈ 0.9)τ的结构和电气性能u2014u2014(p-s s-dmedt-ttf)2(aucl2)(aucl2)y化合物(y≈0.9).pdfVIP
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structural and electrical properties of the τ-(p-s,s-dmedt-ttf)2 (aucl2) (aucl2)y compound with (y ≈ 0.9)τ的结构和电气性能u2014u2014(p-s s-dmedt-ttf)2(aucl2)(aucl2)y化合物(y≈0.9)
Crystals 2012, 2, 1283-1290; doi:10.3390/cryst2031283
OPEN ACCESS
crystals
ISSN 2073-4352
/journal/crystals
Article
Structural and Electrical Properties of the
τ-(P-S,S-DMEDT-TTF) (AuCl ) (AuCl ) Compound
2 2 2 y
with (y ≈ 0.9)
Vassilis Psycharis 1,*, George A. Mousdis 2, Keizo Murata 3 and George C. Papavassiliou 2
1 Institute of Advanced Materials, Physicochemical Processes, Nanotechnology and Microsystems,
Department of Materials Science, National Centre for Scientific Research (NCSR) “Demokritos”,
Aghia Paraskevi Attikis 153 10, Greece
2 Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation,
Athens 11635, Greece; E-Mails: gmousdis@eie.gr (G.A.M.); pseria@eie.gr (G.C.P.)
3 Department of Physics, Graduate School of Science, Osaka City University, Sumiyoshi-ku,
Osaka 558-8585, Japan; E-Mail: muratak@sci.osaka-cu.ac.jp
* Author to whom correspondence should be addressed; E-Mail: vpsychar@ims.demokritos.gr;
Tel.: +30-210-650-3346; Fax: +30-210-651-9430.
Received: 24 May 2012; in revised form: 6 July 2012 / Accepted: 16 August 2012 /
Published: 3 September 2012
Abstract: The compound τ-(P-S,S-DMEDT-TTF) (AuCl ) (AuCl ) (where P-S,S-DMEDT-
2 2 2 y
TTF is the compound pyrazino-(S,S)-dimethyl-ethylenedithio-tetrathiofulvale) crystallizes
in the non-centrosymmetric space group I-42d, with a = 7.3260
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