原创力文档structure-activity relationship of flavonoids active against lard oil oxidation based on quantum chemical analysis构效关系的类黄酮活性对猪油氧化基于量子化学分析.pdfVIP
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structure-activity relationship of flavonoids active against lard oil oxidation based on quantum chemical analysis构效关系的类黄酮活性对猪油氧化基于量子化学分析
Molecules 2009, 14, 46-52; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Communication
Structure-Activity Relationship of Flavonoids Active Against
Lard Oil Oxidation Based on Quantum Chemical Analysis
Ji-Guo Yang 1, Ben-Guo Liu 2,*, Gui-Zhao Liang 3 and Zheng-Xiang Ning 4
1 College of Light Industry and Food Science, South China University of Technology, Guangzhou
510640, P. R. China; E-mail: yjgscut@263.net (J-G. Y.)
2 School of Food Science, Henan Institute of Science and Technology, Xinxiang 453003, P. R. China
3 College of Bioengineering, Chongqing University, Chongqing 400044, P. R. China; E-mail:
gzliang@ (G-Z. L.)
4 College of Light Industry and Food Science, South China University of Technology, Guangzhou
453003, P. R. China; E-mail: fezhning@ (Z-X. N)
* Author to whom correspondence should be addressed; E-mail: zzgclbg@126.com; Tel.: +86-0373-
3040674; Fax: +86-0373-3040709.
Received: 26 November 2008; in revised form: 17 December 2008 / Accepted: 18 December 2008 /
Published: 23 December 2008
Abstract: In this study, the antioxidant activities of 15 flavonoids against lard oil
oxidation were determined by using the Rancimat test. Quercetin, dihydromyricetin,
luteolin and kaempferol showed the strongest antioxidant activity, with protection factor
values (PF) of 11.50, 11.29, 4.24 and 2.49, respectively. The role of conjugated hydroxyl
groups of the B and C ring is discussed. By using the following descriptors: ΔH
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