synthesis and field evaluation of the sex pheromone analogues to soybean pod borer leguminivora glycinivorella性信息素类似物的合成和现场评价大豆pod钻leguminivora glycinivorella.pdfVIP

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synthesis and field evaluation of the sex pheromone analogues to soybean pod borer leguminivora glycinivorella性信息素类似物的合成和现场评价大豆pod钻leguminivora glycinivorella.pdf

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synthesis and field evaluation of the sex pheromone analogues to soybean pod borer leguminivora glycinivorella性信息素类似物的合成和现场评价大豆pod钻leguminivora glycinivorella

Molecules 2012, 17, 12140-12150; doi:10.3390/molecules171012140 OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis and Field Evaluation of the Sex Pheromone Analogues to Soybean Pod Borer Leguminivora glycinivorella Dai-Hua Hu 1,2,3,†,*, Jun He 1,†, Yi-Wan Zhou 1, Jun-Tao Feng 1 and Xing Zhang 1,* 1 Biorational Pesticide Research Development Center, Northwest AF University, Yangling 712100, Shaanxi, China; E-Mails: hejun6206@126.com (J.H.); Yiwan1021@163.com (Y.-W.Z.); jtfeng@126.com (J.-T.F.) 2 Shanxi Research Center of Biopesticide Engineering Technology, Northwest AF University, Yangling 712100, Shaanxi, China 3 School of Chemical Environment Science, Shaanxi University of Technology, Hanzhong 723000, Shaanxi, China † These authors contributed equally to this work. * Authors to whom correspondence should be addressed; E-Mails: hudaihua007@163.com (D.-H.H.); zhxing1952@126.com (X.Z.); Tel./Fax: +86-29-8709-2122 (X.Z.). Received: 4 September 2012; in revised form: 17 September 2012 / Accepted: 21 September 2012 / Published: 16 October 2012 Abstract: In order to develop efficient lures for soybean pod borer Leguminivora glycinivorella (Matsumura) in China, (E,E)-8,10-dodecadienyl acetate (EE- 8,10-12:Ac), the main component of the pheromone of L. glycinivorella, and 12 structurally-related compounds were synthesised in good overall yields, regiospecificities, and stereo-selectivities via coupling reactions catalyse